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1-Ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetrahydro-1H-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6H)-one monohydrate
In the title compound, C(26)H(30)N(2)O(4)S·H(2)O, the pyrrolidine and dihydropyran rings adopt envelope conformations and they are cis-fused. The sulfonyl group has a distorted tetrahedral geometry. In the crystal structure, the molecules are linked into a ribbon-like structure along the a axis b...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970140/ https://www.ncbi.nlm.nih.gov/pubmed/21577515 http://dx.doi.org/10.1107/S1600536809030761 |
Sumario: | In the title compound, C(26)H(30)N(2)O(4)S·H(2)O, the pyrrolidine and dihydropyran rings adopt envelope conformations and they are cis-fused. The sulfonyl group has a distorted tetrahedral geometry. In the crystal structure, the molecules are linked into a ribbon-like structure along the a axis by O/C—H⋯O hydrogen bonds involving water molecules and C—H⋯π interactions involving the sulfonyl-bound phenyl ring. Adjacent ribbons are cross-linked via C—H⋯O hydrogen bonds involving a sulfonyl O atom and C—H⋯π interactions involving the pyridinone ring. |
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