1-Ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetra­hydro-1H-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6H)-one monohydrate

In the title compound, C(26)H(30)N(2)O(4)S·H(2)O, the pyrrolidine and dihydro­pyran rings adopt envelope conformations and they are cis-fused. The sulfonyl group has a distorted tetra­hedral geometry. In the crystal structure, the mol­ecules are linked into a ribbon-like structure along the a axis b...

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Detalles Bibliográficos
Autores principales: Chinnakali, K., Sudha, D., Jayagobi, M., Raghunathan, R., Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970140/
https://www.ncbi.nlm.nih.gov/pubmed/21577515
http://dx.doi.org/10.1107/S1600536809030761
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author Chinnakali, K.
Sudha, D.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
author_facet Chinnakali, K.
Sudha, D.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
author_sort Chinnakali, K.
collection PubMed
description In the title compound, C(26)H(30)N(2)O(4)S·H(2)O, the pyrrolidine and dihydro­pyran rings adopt envelope conformations and they are cis-fused. The sulfonyl group has a distorted tetra­hedral geometry. In the crystal structure, the mol­ecules are linked into a ribbon-like structure along the a axis by O/C—H⋯O hydrogen bonds involving water mol­ecules and C—H⋯π inter­actions involving the sulfonyl-bound phenyl ring. Adjacent ribbons are cross-linked via C—H⋯O hydrogen bonds involving a sulfonyl O atom and C—H⋯π inter­actions involving the pyridinone ring.
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spelling pubmed-29701402010-12-30 1-Ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetra­hydro-1H-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6H)-one monohydrate Chinnakali, K. Sudha, D. Jayagobi, M. Raghunathan, R. Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(30)N(2)O(4)S·H(2)O, the pyrrolidine and dihydro­pyran rings adopt envelope conformations and they are cis-fused. The sulfonyl group has a distorted tetra­hedral geometry. In the crystal structure, the mol­ecules are linked into a ribbon-like structure along the a axis by O/C—H⋯O hydrogen bonds involving water mol­ecules and C—H⋯π inter­actions involving the sulfonyl-bound phenyl ring. Adjacent ribbons are cross-linked via C—H⋯O hydrogen bonds involving a sulfonyl O atom and C—H⋯π inter­actions involving the pyridinone ring. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970140/ /pubmed/21577515 http://dx.doi.org/10.1107/S1600536809030761 Text en © Chinnakali et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chinnakali, K.
Sudha, D.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
1-Ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetra­hydro-1H-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6H)-one monohydrate
title 1-Ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetra­hydro-1H-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6H)-one monohydrate
title_full 1-Ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetra­hydro-1H-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6H)-one monohydrate
title_fullStr 1-Ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetra­hydro-1H-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6H)-one monohydrate
title_full_unstemmed 1-Ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetra­hydro-1H-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6H)-one monohydrate
title_short 1-Ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetra­hydro-1H-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6H)-one monohydrate
title_sort 1-ethyl-2-tosyl-4,4,6-trimethyl-2,3,3a,4-tetra­hydro-1h-pyrrolo[3,4-c]pyrano[6,5-b]quinoline-11(6h)-one monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970140/
https://www.ncbi.nlm.nih.gov/pubmed/21577515
http://dx.doi.org/10.1107/S1600536809030761
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