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Bis{μ-2-[1-(2-Pyridylmethyl­imino)eth­yl]phenolato}bis­[azido­copper(II)]

The title compound, [Cu(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], was synthesized by the reaction of Cu(NO(3))(2)·3H(2)O with the Schiff base 2-[1-(2-pyridylmethyl­imino)eth­yl]phenol (HL) in methanol–water solution, adding NaN(3) as the bridging ligand. The asymmetric unit contains one half-mol­ecule, the...

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Detalles Bibliográficos
Autores principales: Zhang, Jun, Chen, Xiao-Dan, Zhang, Huai-Hong, Sun, Bai-Wang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970141/
https://www.ncbi.nlm.nih.gov/pubmed/21577473
http://dx.doi.org/10.1107/S1600536809030475
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author Zhang, Jun
Chen, Xiao-Dan
Zhang, Huai-Hong
Sun, Bai-Wang
author_facet Zhang, Jun
Chen, Xiao-Dan
Zhang, Huai-Hong
Sun, Bai-Wang
author_sort Zhang, Jun
collection PubMed
description The title compound, [Cu(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], was synthesized by the reaction of Cu(NO(3))(2)·3H(2)O with the Schiff base 2-[1-(2-pyridylmethyl­imino)eth­yl]phenol (HL) in methanol–water solution, adding NaN(3) as the bridging ligand. The asymmetric unit contains one half-mol­ecule, the other half being generated by the inversion center. Each Cu(II) atom shows a slightly distorted trigonal-pyramidal geometry formed by two N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide N atom. The crystal structure is stabilized by intermolecular C—H⋯N hydrogen bonds.
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spelling pubmed-29701412010-12-30 Bis{μ-2-[1-(2-Pyridylmethyl­imino)eth­yl]phenolato}bis­[azido­copper(II)] Zhang, Jun Chen, Xiao-Dan Zhang, Huai-Hong Sun, Bai-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], was synthesized by the reaction of Cu(NO(3))(2)·3H(2)O with the Schiff base 2-[1-(2-pyridylmethyl­imino)eth­yl]phenol (HL) in methanol–water solution, adding NaN(3) as the bridging ligand. The asymmetric unit contains one half-mol­ecule, the other half being generated by the inversion center. Each Cu(II) atom shows a slightly distorted trigonal-pyramidal geometry formed by two N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide N atom. The crystal structure is stabilized by intermolecular C—H⋯N hydrogen bonds. International Union of Crystallography 2009-08-26 /pmc/articles/PMC2970141/ /pubmed/21577473 http://dx.doi.org/10.1107/S1600536809030475 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jun
Chen, Xiao-Dan
Zhang, Huai-Hong
Sun, Bai-Wang
Bis{μ-2-[1-(2-Pyridylmethyl­imino)eth­yl]phenolato}bis­[azido­copper(II)]
title Bis{μ-2-[1-(2-Pyridylmethyl­imino)eth­yl]phenolato}bis­[azido­copper(II)]
title_full Bis{μ-2-[1-(2-Pyridylmethyl­imino)eth­yl]phenolato}bis­[azido­copper(II)]
title_fullStr Bis{μ-2-[1-(2-Pyridylmethyl­imino)eth­yl]phenolato}bis­[azido­copper(II)]
title_full_unstemmed Bis{μ-2-[1-(2-Pyridylmethyl­imino)eth­yl]phenolato}bis­[azido­copper(II)]
title_short Bis{μ-2-[1-(2-Pyridylmethyl­imino)eth­yl]phenolato}bis­[azido­copper(II)]
title_sort bis{μ-2-[1-(2-pyridylmethyl­imino)eth­yl]phenolato}bis­[azido­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970141/
https://www.ncbi.nlm.nih.gov/pubmed/21577473
http://dx.doi.org/10.1107/S1600536809030475
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