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Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)]
The title compound, [Cu(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], was synthesized by the reaction of Cu(NO(3))(2)·3H(2)O with the Schiff base 2-[1-(2-pyridylmethylimino)ethyl]phenol (HL) in methanol–water solution, adding NaN(3) as the bridging ligand. The asymmetric unit contains one half-molecule, the...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970141/ https://www.ncbi.nlm.nih.gov/pubmed/21577473 http://dx.doi.org/10.1107/S1600536809030475 |
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author | Zhang, Jun Chen, Xiao-Dan Zhang, Huai-Hong Sun, Bai-Wang |
author_facet | Zhang, Jun Chen, Xiao-Dan Zhang, Huai-Hong Sun, Bai-Wang |
author_sort | Zhang, Jun |
collection | PubMed |
description | The title compound, [Cu(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], was synthesized by the reaction of Cu(NO(3))(2)·3H(2)O with the Schiff base 2-[1-(2-pyridylmethylimino)ethyl]phenol (HL) in methanol–water solution, adding NaN(3) as the bridging ligand. The asymmetric unit contains one half-molecule, the other half being generated by the inversion center. Each Cu(II) atom shows a slightly distorted trigonal-pyramidal geometry formed by two N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide N atom. The crystal structure is stabilized by intermolecular C—H⋯N hydrogen bonds. |
format | Text |
id | pubmed-2970141 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29701412010-12-30 Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)] Zhang, Jun Chen, Xiao-Dan Zhang, Huai-Hong Sun, Bai-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], was synthesized by the reaction of Cu(NO(3))(2)·3H(2)O with the Schiff base 2-[1-(2-pyridylmethylimino)ethyl]phenol (HL) in methanol–water solution, adding NaN(3) as the bridging ligand. The asymmetric unit contains one half-molecule, the other half being generated by the inversion center. Each Cu(II) atom shows a slightly distorted trigonal-pyramidal geometry formed by two N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide N atom. The crystal structure is stabilized by intermolecular C—H⋯N hydrogen bonds. International Union of Crystallography 2009-08-26 /pmc/articles/PMC2970141/ /pubmed/21577473 http://dx.doi.org/10.1107/S1600536809030475 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Jun Chen, Xiao-Dan Zhang, Huai-Hong Sun, Bai-Wang Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)] |
title | Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)] |
title_full | Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)] |
title_fullStr | Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)] |
title_full_unstemmed | Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)] |
title_short | Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)] |
title_sort | bis{μ-2-[1-(2-pyridylmethylimino)ethyl]phenolato}bis[azidocopper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970141/ https://www.ncbi.nlm.nih.gov/pubmed/21577473 http://dx.doi.org/10.1107/S1600536809030475 |
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