Bis{2-meth­oxy-6-[(3-pyrid­yl)methyl­imino­meth­yl]phenolato}copper(II)

In the mononuclear title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) atom lies on an inversion centre and adopts a square-planar coordination geometry. The dihedral angle formed by the pyridine and benzene rings is 74.61 (5)°. Intra­molecular C—H⋯O hydrogen bonds are present. The crystal struct...

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Detalles Bibliográficos
Autores principales: Wang, Yun, Zhu, Li-Li, Sun, Bai-Wang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970154/
https://www.ncbi.nlm.nih.gov/pubmed/21577417
http://dx.doi.org/10.1107/S1600536809029523
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author Wang, Yun
Zhu, Li-Li
Sun, Bai-Wang
author_facet Wang, Yun
Zhu, Li-Li
Sun, Bai-Wang
author_sort Wang, Yun
collection PubMed
description In the mononuclear title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) atom lies on an inversion centre and adopts a square-planar coordination geometry. The dihedral angle formed by the pyridine and benzene rings is 74.61 (5)°. Intra­molecular C—H⋯O hydrogen bonds are present. The crystal structure is stabilized by weak aromatic π–π stacking inter­actions involving neighbouring pyridine rings [centroid–centroid distance = 3.853 (2) Å].
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spelling pubmed-29701542010-12-30 Bis{2-meth­oxy-6-[(3-pyrid­yl)methyl­imino­meth­yl]phenolato}copper(II) Wang, Yun Zhu, Li-Li Sun, Bai-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) atom lies on an inversion centre and adopts a square-planar coordination geometry. The dihedral angle formed by the pyridine and benzene rings is 74.61 (5)°. Intra­molecular C—H⋯O hydrogen bonds are present. The crystal structure is stabilized by weak aromatic π–π stacking inter­actions involving neighbouring pyridine rings [centroid–centroid distance = 3.853 (2) Å]. International Union of Crystallography 2009-08-12 /pmc/articles/PMC2970154/ /pubmed/21577417 http://dx.doi.org/10.1107/S1600536809029523 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yun
Zhu, Li-Li
Sun, Bai-Wang
Bis{2-meth­oxy-6-[(3-pyrid­yl)methyl­imino­meth­yl]phenolato}copper(II)
title Bis{2-meth­oxy-6-[(3-pyrid­yl)methyl­imino­meth­yl]phenolato}copper(II)
title_full Bis{2-meth­oxy-6-[(3-pyrid­yl)methyl­imino­meth­yl]phenolato}copper(II)
title_fullStr Bis{2-meth­oxy-6-[(3-pyrid­yl)methyl­imino­meth­yl]phenolato}copper(II)
title_full_unstemmed Bis{2-meth­oxy-6-[(3-pyrid­yl)methyl­imino­meth­yl]phenolato}copper(II)
title_short Bis{2-meth­oxy-6-[(3-pyrid­yl)methyl­imino­meth­yl]phenolato}copper(II)
title_sort bis{2-meth­oxy-6-[(3-pyrid­yl)methyl­imino­meth­yl]phenolato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970154/
https://www.ncbi.nlm.nih.gov/pubmed/21577417
http://dx.doi.org/10.1107/S1600536809029523
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AT sunbaiwang bis2methoxy63pyridylmethyliminomethylphenolatocopperii

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