Poly[[diaqua­(ethanol)bis­(μ(3)-pyridine-2,3-dicarboxyl­ato)dimanganese(II)] monohydrate]

The title compound, {[Mn(2)(C(7)H(3)NO(4))(2)(C(2)H(5)OH)(H(2)O)(2)]·H(2)O}(n), is a three-dimensional polymer. There are two symmetry-independent Mn(II) centres with different coordination environments: one Mn(II) atom is coordinated by four O atoms from four ligands and two N atoms from two ligand...

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Detalles Bibliográficos
Autor principal: Zhao, Yan-Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970155/
https://www.ncbi.nlm.nih.gov/pubmed/21577443
http://dx.doi.org/10.1107/S1600536809031948
Descripción
Sumario:The title compound, {[Mn(2)(C(7)H(3)NO(4))(2)(C(2)H(5)OH)(H(2)O)(2)]·H(2)O}(n), is a three-dimensional polymer. There are two symmetry-independent Mn(II) centres with different coordination environments: one Mn(II) atom is coordinated by four O atoms from four ligands and two N atoms from two ligands, the other Mn(II) atom is coordinated by three O atoms from two ligands, two water O atoms and the O atom of an ethanol mol­ecule. The crystal structure is stabilized by O—H⋯O hydrogen bonds.

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