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2,2-Dimethyl-5-[(3-nitroanilino)methylene]-1,3-dioxane-4,6-dione
The benzene ring of the title compound, C(13)H(12)N(2)O(6), is twisted away from the planes of the aminomethylene unit and the dioxane ring by 30.13 (4) and 35.89 (4)°, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.553 (8) Å...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970156/ https://www.ncbi.nlm.nih.gov/pubmed/21577577 http://dx.doi.org/10.1107/S1600536809031535 |
Sumario: | The benzene ring of the title compound, C(13)H(12)N(2)O(6), is twisted away from the planes of the aminomethylene unit and the dioxane ring by 30.13 (4) and 35.89 (4)°, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.553 (8) Å out-of-plane. An intramolecular N—H⋯O hydrogen bond stabilizes the conformation of the dioxane ring with the aminomethylene group [the dihedral angle between the mean planes of the dioxane ring and the aminomethylene group is 11.61 (4)°]. In the crystal, a three-dimensional framework is built via weak intermolecular N—H⋯O and C—H⋯O interactions. |
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