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2,2-Dimethyl-5-[(3-nitro­anilino)methyl­ene]-1,3-dioxane-4,6-dione

The benzene ring of the title compound, C(13)H(12)N(2)O(6), is twisted away from the planes of the amino­methyl­ene unit and the dioxane ring by 30.13 (4) and 35.89 (4)°, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.553 (8) Å...

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Detalles Bibliográficos
Autores principales: Zhou, Meng, Li, Rui, Ding, Zhen-Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970156/
https://www.ncbi.nlm.nih.gov/pubmed/21577577
http://dx.doi.org/10.1107/S1600536809031535
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author Zhou, Meng
Li, Rui
Ding, Zhen-Yu
author_facet Zhou, Meng
Li, Rui
Ding, Zhen-Yu
author_sort Zhou, Meng
collection PubMed
description The benzene ring of the title compound, C(13)H(12)N(2)O(6), is twisted away from the planes of the amino­methyl­ene unit and the dioxane ring by 30.13 (4) and 35.89 (4)°, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.553 (8) Å out-of-plane. An intra­molecular N—H⋯O hydrogen bond stabilizes the conformation of the dioxane ring with the amino­methyl­ene group [the dihedral angle between the mean planes of the dioxane ring and the amino­methyl­ene group is 11.61 (4)°]. In the crystal, a three-dimensional framework is built via weak inter­molecular N—H⋯O and C—H⋯O inter­actions.
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spelling pubmed-29701562010-12-30 2,2-Dimethyl-5-[(3-nitro­anilino)methyl­ene]-1,3-dioxane-4,6-dione Zhou, Meng Li, Rui Ding, Zhen-Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers The benzene ring of the title compound, C(13)H(12)N(2)O(6), is twisted away from the planes of the amino­methyl­ene unit and the dioxane ring by 30.13 (4) and 35.89 (4)°, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.553 (8) Å out-of-plane. An intra­molecular N—H⋯O hydrogen bond stabilizes the conformation of the dioxane ring with the amino­methyl­ene group [the dihedral angle between the mean planes of the dioxane ring and the amino­methyl­ene group is 11.61 (4)°]. In the crystal, a three-dimensional framework is built via weak inter­molecular N—H⋯O and C—H⋯O inter­actions. International Union of Crystallography 2009-08-15 /pmc/articles/PMC2970156/ /pubmed/21577577 http://dx.doi.org/10.1107/S1600536809031535 Text en © Zhou et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhou, Meng
Li, Rui
Ding, Zhen-Yu
2,2-Dimethyl-5-[(3-nitro­anilino)methyl­ene]-1,3-dioxane-4,6-dione
title 2,2-Dimethyl-5-[(3-nitro­anilino)methyl­ene]-1,3-dioxane-4,6-dione
title_full 2,2-Dimethyl-5-[(3-nitro­anilino)methyl­ene]-1,3-dioxane-4,6-dione
title_fullStr 2,2-Dimethyl-5-[(3-nitro­anilino)methyl­ene]-1,3-dioxane-4,6-dione
title_full_unstemmed 2,2-Dimethyl-5-[(3-nitro­anilino)methyl­ene]-1,3-dioxane-4,6-dione
title_short 2,2-Dimethyl-5-[(3-nitro­anilino)methyl­ene]-1,3-dioxane-4,6-dione
title_sort 2,2-dimethyl-5-[(3-nitro­anilino)methyl­ene]-1,3-dioxane-4,6-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970156/
https://www.ncbi.nlm.nih.gov/pubmed/21577577
http://dx.doi.org/10.1107/S1600536809031535
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