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2,2-Dimethyl-5-[(3-nitroanilino)methylene]-1,3-dioxane-4,6-dione
The benzene ring of the title compound, C(13)H(12)N(2)O(6), is twisted away from the planes of the aminomethylene unit and the dioxane ring by 30.13 (4) and 35.89 (4)°, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.553 (8) Å...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970156/ https://www.ncbi.nlm.nih.gov/pubmed/21577577 http://dx.doi.org/10.1107/S1600536809031535 |
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author | Zhou, Meng Li, Rui Ding, Zhen-Yu |
author_facet | Zhou, Meng Li, Rui Ding, Zhen-Yu |
author_sort | Zhou, Meng |
collection | PubMed |
description | The benzene ring of the title compound, C(13)H(12)N(2)O(6), is twisted away from the planes of the aminomethylene unit and the dioxane ring by 30.13 (4) and 35.89 (4)°, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.553 (8) Å out-of-plane. An intramolecular N—H⋯O hydrogen bond stabilizes the conformation of the dioxane ring with the aminomethylene group [the dihedral angle between the mean planes of the dioxane ring and the aminomethylene group is 11.61 (4)°]. In the crystal, a three-dimensional framework is built via weak intermolecular N—H⋯O and C—H⋯O interactions. |
format | Text |
id | pubmed-2970156 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29701562010-12-30 2,2-Dimethyl-5-[(3-nitroanilino)methylene]-1,3-dioxane-4,6-dione Zhou, Meng Li, Rui Ding, Zhen-Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers The benzene ring of the title compound, C(13)H(12)N(2)O(6), is twisted away from the planes of the aminomethylene unit and the dioxane ring by 30.13 (4) and 35.89 (4)°, respectively. The dioxane ring exhibits a half-boat conformation, in which the C atom between the dioxane O atoms is 0.553 (8) Å out-of-plane. An intramolecular N—H⋯O hydrogen bond stabilizes the conformation of the dioxane ring with the aminomethylene group [the dihedral angle between the mean planes of the dioxane ring and the aminomethylene group is 11.61 (4)°]. In the crystal, a three-dimensional framework is built via weak intermolecular N—H⋯O and C—H⋯O interactions. International Union of Crystallography 2009-08-15 /pmc/articles/PMC2970156/ /pubmed/21577577 http://dx.doi.org/10.1107/S1600536809031535 Text en © Zhou et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhou, Meng Li, Rui Ding, Zhen-Yu 2,2-Dimethyl-5-[(3-nitroanilino)methylene]-1,3-dioxane-4,6-dione |
title | 2,2-Dimethyl-5-[(3-nitroanilino)methylene]-1,3-dioxane-4,6-dione |
title_full | 2,2-Dimethyl-5-[(3-nitroanilino)methylene]-1,3-dioxane-4,6-dione |
title_fullStr | 2,2-Dimethyl-5-[(3-nitroanilino)methylene]-1,3-dioxane-4,6-dione |
title_full_unstemmed | 2,2-Dimethyl-5-[(3-nitroanilino)methylene]-1,3-dioxane-4,6-dione |
title_short | 2,2-Dimethyl-5-[(3-nitroanilino)methylene]-1,3-dioxane-4,6-dione |
title_sort | 2,2-dimethyl-5-[(3-nitroanilino)methylene]-1,3-dioxane-4,6-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970156/ https://www.ncbi.nlm.nih.gov/pubmed/21577577 http://dx.doi.org/10.1107/S1600536809031535 |
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