cis-Dichloridobis(triphenyl­phosphine-κP)platinum(II) chloro­form solvate

In the title compound, [PtCl(2)(C(18)H(15)P)(2)]·CHCl(3), each Pt(II) centre adopts a nearly square-planar coordination geometry formed by two P atoms [Pt—P = 2.2481 (17) and 2.2658 (19) Å] and two Cl anions [Pt—Cl = 2.3244 (19) and 2.3548 (17) Å]. The Cl atoms of the chloro­form solvent mol­ecule a...

Descripción completa

Detalles Bibliográficos
Autores principales: Miao, Jinling, Hu, Chunhua, Feng, Xiao, Chen, Hongwei, Nie, Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970157/
https://www.ncbi.nlm.nih.gov/pubmed/21577392
http://dx.doi.org/10.1107/S1600536809029961
Descripción
Sumario:In the title compound, [PtCl(2)(C(18)H(15)P)(2)]·CHCl(3), each Pt(II) centre adopts a nearly square-planar coordination geometry formed by two P atoms [Pt—P = 2.2481 (17) and 2.2658 (19) Å] and two Cl anions [Pt—Cl = 2.3244 (19) and 2.3548 (17) Å]. The Cl atoms of the chloro­form solvent mol­ecule are disordered over two orientations in a 0.778 (11):0.222 (11) ratio. The crystal packing is stabilized by weak inter­molecular C—H⋯Cl hydrogen bonds, exhib­iting voids with a volume of 215 Å(3).

Ejemplares similares