cis-Dichloridobis(triphenyl­phosphine-κP)platinum(II) chloro­form solvate

In the title compound, [PtCl(2)(C(18)H(15)P)(2)]·CHCl(3), each Pt(II) centre adopts a nearly square-planar coordination geometry formed by two P atoms [Pt—P = 2.2481 (17) and 2.2658 (19) Å] and two Cl anions [Pt—Cl = 2.3244 (19) and 2.3548 (17) Å]. The Cl atoms of the chloro­form solvent mol­ecule a...

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Detalles Bibliográficos
Autores principales: Miao, Jinling, Hu, Chunhua, Feng, Xiao, Chen, Hongwei, Nie, Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970157/
https://www.ncbi.nlm.nih.gov/pubmed/21577392
http://dx.doi.org/10.1107/S1600536809029961
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author Miao, Jinling
Hu, Chunhua
Feng, Xiao
Chen, Hongwei
Nie, Yong
author_facet Miao, Jinling
Hu, Chunhua
Feng, Xiao
Chen, Hongwei
Nie, Yong
author_sort Miao, Jinling
collection PubMed
description In the title compound, [PtCl(2)(C(18)H(15)P)(2)]·CHCl(3), each Pt(II) centre adopts a nearly square-planar coordination geometry formed by two P atoms [Pt—P = 2.2481 (17) and 2.2658 (19) Å] and two Cl anions [Pt—Cl = 2.3244 (19) and 2.3548 (17) Å]. The Cl atoms of the chloro­form solvent mol­ecule are disordered over two orientations in a 0.778 (11):0.222 (11) ratio. The crystal packing is stabilized by weak inter­molecular C—H⋯Cl hydrogen bonds, exhib­iting voids with a volume of 215 Å(3).
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spelling pubmed-29701572010-12-30 cis-Dichloridobis(triphenyl­phosphine-κP)platinum(II) chloro­form solvate Miao, Jinling Hu, Chunhua Feng, Xiao Chen, Hongwei Nie, Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PtCl(2)(C(18)H(15)P)(2)]·CHCl(3), each Pt(II) centre adopts a nearly square-planar coordination geometry formed by two P atoms [Pt—P = 2.2481 (17) and 2.2658 (19) Å] and two Cl anions [Pt—Cl = 2.3244 (19) and 2.3548 (17) Å]. The Cl atoms of the chloro­form solvent mol­ecule are disordered over two orientations in a 0.778 (11):0.222 (11) ratio. The crystal packing is stabilized by weak inter­molecular C—H⋯Cl hydrogen bonds, exhib­iting voids with a volume of 215 Å(3). International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970157/ /pubmed/21577392 http://dx.doi.org/10.1107/S1600536809029961 Text en © Miao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Miao, Jinling
Hu, Chunhua
Feng, Xiao
Chen, Hongwei
Nie, Yong
cis-Dichloridobis(triphenyl­phosphine-κP)platinum(II) chloro­form solvate
title cis-Dichloridobis(triphenyl­phosphine-κP)platinum(II) chloro­form solvate
title_full cis-Dichloridobis(triphenyl­phosphine-κP)platinum(II) chloro­form solvate
title_fullStr cis-Dichloridobis(triphenyl­phosphine-κP)platinum(II) chloro­form solvate
title_full_unstemmed cis-Dichloridobis(triphenyl­phosphine-κP)platinum(II) chloro­form solvate
title_short cis-Dichloridobis(triphenyl­phosphine-κP)platinum(II) chloro­form solvate
title_sort cis-dichloridobis(triphenyl­phosphine-κp)platinum(ii) chloro­form solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970157/
https://www.ncbi.nlm.nih.gov/pubmed/21577392
http://dx.doi.org/10.1107/S1600536809029961
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AT huchunhua cisdichloridobistriphenylphosphinekpplatinumiichloroformsolvate
AT fengxiao cisdichloridobistriphenylphosphinekpplatinumiichloroformsolvate
AT chenhongwei cisdichloridobistriphenylphosphinekpplatinumiichloroformsolvate
AT nieyong cisdichloridobistriphenylphosphinekpplatinumiichloroformsolvate

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