4-(Benzyl­ideneamino)benzene­sulfonamide

The title compound, C(13)H(12)N(2)O(2)S, formed by Schiff base condensation of benzaldehyde with sulfanilamide, crystallizes as discrete mol­ecular species linked by N—H⋯N and N—H⋯O hydrogen bonds between the sulfamide nitro­gen H atoms and the aza­methine N and one sulfamide O atom, respectively, f...

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Detalles Bibliográficos
Autores principales: Loughrey, Bradley T., Williams, Michael L., Healy, Peter C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970159/
https://www.ncbi.nlm.nih.gov/pubmed/21577505
http://dx.doi.org/10.1107/S1600536809030256
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author Loughrey, Bradley T.
Williams, Michael L.
Healy, Peter C.
author_facet Loughrey, Bradley T.
Williams, Michael L.
Healy, Peter C.
author_sort Loughrey, Bradley T.
collection PubMed
description The title compound, C(13)H(12)N(2)O(2)S, formed by Schiff base condensation of benzaldehyde with sulfanilamide, crystallizes as discrete mol­ecular species linked by N—H⋯N and N—H⋯O hydrogen bonds between the sulfamide nitro­gen H atoms and the aza­methine N and one sulfamide O atom, respectively, forming a two-dimensional array in the bc plane. The aza­methine group is rotated slightly out of the benzaldehyde benzene plane [C—C—C—N torsion angle = 8.1 (3)°], while the dihedral angle between the two benzene rings is 30.0 (1)°.
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spelling pubmed-29701592010-12-30 4-(Benzyl­ideneamino)benzene­sulfonamide Loughrey, Bradley T. Williams, Michael L. Healy, Peter C. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(12)N(2)O(2)S, formed by Schiff base condensation of benzaldehyde with sulfanilamide, crystallizes as discrete mol­ecular species linked by N—H⋯N and N—H⋯O hydrogen bonds between the sulfamide nitro­gen H atoms and the aza­methine N and one sulfamide O atom, respectively, forming a two-dimensional array in the bc plane. The aza­methine group is rotated slightly out of the benzaldehyde benzene plane [C—C—C—N torsion angle = 8.1 (3)°], while the dihedral angle between the two benzene rings is 30.0 (1)°. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970159/ /pubmed/21577505 http://dx.doi.org/10.1107/S1600536809030256 Text en © Loughrey et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Loughrey, Bradley T.
Williams, Michael L.
Healy, Peter C.
4-(Benzyl­ideneamino)benzene­sulfonamide
title 4-(Benzyl­ideneamino)benzene­sulfonamide
title_full 4-(Benzyl­ideneamino)benzene­sulfonamide
title_fullStr 4-(Benzyl­ideneamino)benzene­sulfonamide
title_full_unstemmed 4-(Benzyl­ideneamino)benzene­sulfonamide
title_short 4-(Benzyl­ideneamino)benzene­sulfonamide
title_sort 4-(benzyl­ideneamino)benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970159/
https://www.ncbi.nlm.nih.gov/pubmed/21577505
http://dx.doi.org/10.1107/S1600536809030256
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AT healypeterc 4benzylideneaminobenzenesulfonamide

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