Tetra-μ-oxido-tetra­kis{dioxido[3-(2-pyrid­yl)-1H-pyrazole]molybdenum(VI)}

In the title compound, [Mo(4)O(12)(C(8)H(7)N(3))(4)], the Mo(VI) ion has a distorted octa­hedral coordination completed by two terminal O atoms, two μ-oxide atoms and two N atoms from one 3-(2-pyrid­yl)-1H-pyrazole ligand. It is noteworthy that in the tetranuclear unit ([Image: see text] symmetry),...

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Detalles Bibliográficos
Autores principales: Li, Dacheng, Liu, Ying, Wei, Peihai, Hu, Bo, Zhang, Xiutang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970160/
https://www.ncbi.nlm.nih.gov/pubmed/21577428
http://dx.doi.org/10.1107/S1600536809031717
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author Li, Dacheng
Liu, Ying
Wei, Peihai
Hu, Bo
Zhang, Xiutang
author_facet Li, Dacheng
Liu, Ying
Wei, Peihai
Hu, Bo
Zhang, Xiutang
author_sort Li, Dacheng
collection PubMed
description In the title compound, [Mo(4)O(12)(C(8)H(7)N(3))(4)], the Mo(VI) ion has a distorted octa­hedral coordination completed by two terminal O atoms, two μ-oxide atoms and two N atoms from one 3-(2-pyrid­yl)-1H-pyrazole ligand. It is noteworthy that in the tetranuclear unit ([Image: see text] symmetry), any three Mo(VI) atoms define a plane, and the fourth lies 1.8 (1) Å out of that plane. The degree of linearity of the oxide bridges between two Mo atoms is 175.38 (13)°. Moreover, the N—H group forms an intra­molecular hydrogen bond (four per mol­ecule).
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spelling pubmed-29701602010-12-30 Tetra-μ-oxido-tetra­kis{dioxido[3-(2-pyrid­yl)-1H-pyrazole]molybdenum(VI)} Li, Dacheng Liu, Ying Wei, Peihai Hu, Bo Zhang, Xiutang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mo(4)O(12)(C(8)H(7)N(3))(4)], the Mo(VI) ion has a distorted octa­hedral coordination completed by two terminal O atoms, two μ-oxide atoms and two N atoms from one 3-(2-pyrid­yl)-1H-pyrazole ligand. It is noteworthy that in the tetranuclear unit ([Image: see text] symmetry), any three Mo(VI) atoms define a plane, and the fourth lies 1.8 (1) Å out of that plane. The degree of linearity of the oxide bridges between two Mo atoms is 175.38 (13)°. Moreover, the N—H group forms an intra­molecular hydrogen bond (four per mol­ecule). International Union of Crystallography 2009-08-15 /pmc/articles/PMC2970160/ /pubmed/21577428 http://dx.doi.org/10.1107/S1600536809031717 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Dacheng
Liu, Ying
Wei, Peihai
Hu, Bo
Zhang, Xiutang
Tetra-μ-oxido-tetra­kis{dioxido[3-(2-pyrid­yl)-1H-pyrazole]molybdenum(VI)}
title Tetra-μ-oxido-tetra­kis{dioxido[3-(2-pyrid­yl)-1H-pyrazole]molybdenum(VI)}
title_full Tetra-μ-oxido-tetra­kis{dioxido[3-(2-pyrid­yl)-1H-pyrazole]molybdenum(VI)}
title_fullStr Tetra-μ-oxido-tetra­kis{dioxido[3-(2-pyrid­yl)-1H-pyrazole]molybdenum(VI)}
title_full_unstemmed Tetra-μ-oxido-tetra­kis{dioxido[3-(2-pyrid­yl)-1H-pyrazole]molybdenum(VI)}
title_short Tetra-μ-oxido-tetra­kis{dioxido[3-(2-pyrid­yl)-1H-pyrazole]molybdenum(VI)}
title_sort tetra-μ-oxido-tetra­kis{dioxido[3-(2-pyrid­yl)-1h-pyrazole]molybdenum(vi)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970160/
https://www.ncbi.nlm.nih.gov/pubmed/21577428
http://dx.doi.org/10.1107/S1600536809031717
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