Bis(1-carbamimidoyl-2-ethyl­isourea)copper(II) bis­(perchlorate)

The title complex, [Cu(C(4)H(10)N(4)O)(2)](ClO(4))(2) or [Cu(L (1e))(2)](ClO(4))(2), where L (1e) is 1-carbamimidoyl-2-ethyl­isourea, was obtained from the ethano­lysis reaction of 2-cyano­guanidine and copper(II) perchlorate hexa­hydrate in a 2:1 molar ratio. The two bidentate L (1e) ligands are co...

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Detalles Bibliográficos
Autores principales: Meenongwa, Atittaya, Chaveerach, Unchulee, Wilson, Claire, Blake, Alexander J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970167/
https://www.ncbi.nlm.nih.gov/pubmed/21577707
http://dx.doi.org/10.1107/S1600536809034965
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author Meenongwa, Atittaya
Chaveerach, Unchulee
Wilson, Claire
Blake, Alexander J.
author_facet Meenongwa, Atittaya
Chaveerach, Unchulee
Wilson, Claire
Blake, Alexander J.
author_sort Meenongwa, Atittaya
collection PubMed
description The title complex, [Cu(C(4)H(10)N(4)O)(2)](ClO(4))(2) or [Cu(L (1e))(2)](ClO(4))(2), where L (1e) is 1-carbamimidoyl-2-ethyl­isourea, was obtained from the ethano­lysis reaction of 2-cyano­guanidine and copper(II) perchlorate hexa­hydrate in a 2:1 molar ratio. The two bidentate L (1e) ligands are coordinated to the Cu(II) center through N-donor atoms, leading to the CuN(4) chromophore. The Cu(II) environment is slightly distorted square-planar, with a dihedral angle of 5.17 (6)° between the two six-membered chelate rings. One of the ClO(4) (−) anions is disordered over two positions in a 0.6:0.4 ratio.
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spelling pubmed-29701672010-12-30 Bis(1-carbamimidoyl-2-ethyl­isourea)copper(II) bis­(perchlorate) Meenongwa, Atittaya Chaveerach, Unchulee Wilson, Claire Blake, Alexander J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(4)H(10)N(4)O)(2)](ClO(4))(2) or [Cu(L (1e))(2)](ClO(4))(2), where L (1e) is 1-carbamimidoyl-2-ethyl­isourea, was obtained from the ethano­lysis reaction of 2-cyano­guanidine and copper(II) perchlorate hexa­hydrate in a 2:1 molar ratio. The two bidentate L (1e) ligands are coordinated to the Cu(II) center through N-donor atoms, leading to the CuN(4) chromophore. The Cu(II) environment is slightly distorted square-planar, with a dihedral angle of 5.17 (6)° between the two six-membered chelate rings. One of the ClO(4) (−) anions is disordered over two positions in a 0.6:0.4 ratio. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970167/ /pubmed/21577707 http://dx.doi.org/10.1107/S1600536809034965 Text en © Meenongwa et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meenongwa, Atittaya
Chaveerach, Unchulee
Wilson, Claire
Blake, Alexander J.
Bis(1-carbamimidoyl-2-ethyl­isourea)copper(II) bis­(perchlorate)
title Bis(1-carbamimidoyl-2-ethyl­isourea)copper(II) bis­(perchlorate)
title_full Bis(1-carbamimidoyl-2-ethyl­isourea)copper(II) bis­(perchlorate)
title_fullStr Bis(1-carbamimidoyl-2-ethyl­isourea)copper(II) bis­(perchlorate)
title_full_unstemmed Bis(1-carbamimidoyl-2-ethyl­isourea)copper(II) bis­(perchlorate)
title_short Bis(1-carbamimidoyl-2-ethyl­isourea)copper(II) bis­(perchlorate)
title_sort bis(1-carbamimidoyl-2-ethyl­isourea)copper(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970167/
https://www.ncbi.nlm.nih.gov/pubmed/21577707
http://dx.doi.org/10.1107/S1600536809034965
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AT wilsonclaire bis1carbamimidoyl2ethylisoureacopperiibisperchlorate
AT blakealexanderj bis1carbamimidoyl2ethylisoureacopperiibisperchlorate

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