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Tris(ethylenediamine)manganese(II) sulfate
In the title compound, [Mn(C(2)H(8)N(2))(3)]SO(4), the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethylenediamine (en) ligands in a slightly distorted octahedral geometry. The en ligands are generated from one half-molecule in the asymmetric unit. The O atoms of the s...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970169/ https://www.ncbi.nlm.nih.gov/pubmed/21577720 http://dx.doi.org/10.1107/S1600536809034874 |
Sumario: | In the title compound, [Mn(C(2)H(8)N(2))(3)]SO(4), the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethylenediamine (en) ligands in a slightly distorted octahedral geometry. The en ligands are generated from one half-molecule in the asymmetric unit. The O atoms of the sulfate anion (S site symmetry 3.2) are disordered over four orientations in a 0.220 (12):0.210 (13):0.203 (14):0.10 (2) ratio, with one of the O atoms having site symmetry 3. In the crystal, the ions are connected by N—H⋯O hydrogen bonds, forming a three-dimensional network. |
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