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Tris(ethyl­enediamine)manganese(II) sulfate

In the title compound, [Mn(C(2)H(8)N(2))(3)]SO(4), the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethyl­enediamine (en) ligands in a slightly distorted octa­hedral geometry. The en ligands are generated from one half-mol­ecule in the asymmetric unit. The O atoms of the s...

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Autor principal: Lu, Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970169/
https://www.ncbi.nlm.nih.gov/pubmed/21577720
http://dx.doi.org/10.1107/S1600536809034874
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author Lu, Jing
author_facet Lu, Jing
author_sort Lu, Jing
collection PubMed
description In the title compound, [Mn(C(2)H(8)N(2))(3)]SO(4), the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethyl­enediamine (en) ligands in a slightly distorted octa­hedral geometry. The en ligands are generated from one half-mol­ecule in the asymmetric unit. The O atoms of the sulfate anion (S site symmetry 3.2) are disordered over four orientations in a 0.220 (12):0.210 (13):0.203 (14):0.10 (2) ratio, with one of the O atoms having site symmetry 3. In the crystal, the ions are connected by N—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-29701692010-12-30 Tris(ethyl­enediamine)manganese(II) sulfate Lu, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(2)H(8)N(2))(3)]SO(4), the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethyl­enediamine (en) ligands in a slightly distorted octa­hedral geometry. The en ligands are generated from one half-mol­ecule in the asymmetric unit. The O atoms of the sulfate anion (S site symmetry 3.2) are disordered over four orientations in a 0.220 (12):0.210 (13):0.203 (14):0.10 (2) ratio, with one of the O atoms having site symmetry 3. In the crystal, the ions are connected by N—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970169/ /pubmed/21577720 http://dx.doi.org/10.1107/S1600536809034874 Text en © Jing Lu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lu, Jing
Tris(ethyl­enediamine)manganese(II) sulfate
title Tris(ethyl­enediamine)manganese(II) sulfate
title_full Tris(ethyl­enediamine)manganese(II) sulfate
title_fullStr Tris(ethyl­enediamine)manganese(II) sulfate
title_full_unstemmed Tris(ethyl­enediamine)manganese(II) sulfate
title_short Tris(ethyl­enediamine)manganese(II) sulfate
title_sort tris(ethyl­enediamine)manganese(ii) sulfate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970169/
https://www.ncbi.nlm.nih.gov/pubmed/21577720
http://dx.doi.org/10.1107/S1600536809034874
work_keys_str_mv AT lujing trisethylenediaminemanganeseiisulfate