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Tris(ethylenediamine)manganese(II) sulfate
In the title compound, [Mn(C(2)H(8)N(2))(3)]SO(4), the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethylenediamine (en) ligands in a slightly distorted octahedral geometry. The en ligands are generated from one half-molecule in the asymmetric unit. The O atoms of the s...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970169/ https://www.ncbi.nlm.nih.gov/pubmed/21577720 http://dx.doi.org/10.1107/S1600536809034874 |
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author | Lu, Jing |
author_facet | Lu, Jing |
author_sort | Lu, Jing |
collection | PubMed |
description | In the title compound, [Mn(C(2)H(8)N(2))(3)]SO(4), the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethylenediamine (en) ligands in a slightly distorted octahedral geometry. The en ligands are generated from one half-molecule in the asymmetric unit. The O atoms of the sulfate anion (S site symmetry 3.2) are disordered over four orientations in a 0.220 (12):0.210 (13):0.203 (14):0.10 (2) ratio, with one of the O atoms having site symmetry 3. In the crystal, the ions are connected by N—H⋯O hydrogen bonds, forming a three-dimensional network. |
format | Text |
id | pubmed-2970169 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29701692010-12-30 Tris(ethylenediamine)manganese(II) sulfate Lu, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(2)H(8)N(2))(3)]SO(4), the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethylenediamine (en) ligands in a slightly distorted octahedral geometry. The en ligands are generated from one half-molecule in the asymmetric unit. The O atoms of the sulfate anion (S site symmetry 3.2) are disordered over four orientations in a 0.220 (12):0.210 (13):0.203 (14):0.10 (2) ratio, with one of the O atoms having site symmetry 3. In the crystal, the ions are connected by N—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970169/ /pubmed/21577720 http://dx.doi.org/10.1107/S1600536809034874 Text en © Jing Lu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lu, Jing Tris(ethylenediamine)manganese(II) sulfate |
title | Tris(ethylenediamine)manganese(II) sulfate |
title_full | Tris(ethylenediamine)manganese(II) sulfate |
title_fullStr | Tris(ethylenediamine)manganese(II) sulfate |
title_full_unstemmed | Tris(ethylenediamine)manganese(II) sulfate |
title_short | Tris(ethylenediamine)manganese(II) sulfate |
title_sort | tris(ethylenediamine)manganese(ii) sulfate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970169/ https://www.ncbi.nlm.nih.gov/pubmed/21577720 http://dx.doi.org/10.1107/S1600536809034874 |
work_keys_str_mv | AT lujing trisethylenediaminemanganeseiisulfate |