1-Bromo-1′-(diphenyl­thio­phosphor­yl)­ferrocene

The title compound, [Fe(C(5)H(4)Br)(C(17)H(14)PS)], crystallizes with two practically undistiguishable mol­ecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1′-diyl units exhibit a regular geometry with negligible tilting and balanced Fe–ring centroid d...

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Detalles Bibliográficos
Autores principales: Štěpnička, Petr, Schulz, Jiří, Císařová, Ivana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970171/
https://www.ncbi.nlm.nih.gov/pubmed/21577736
http://dx.doi.org/10.1107/S1600536809036459
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author Štěpnička, Petr
Schulz, Jiří
Císařová, Ivana
author_facet Štěpnička, Petr
Schulz, Jiří
Císařová, Ivana
author_sort Štěpnička, Petr
collection PubMed
description The title compound, [Fe(C(5)H(4)Br)(C(17)H(14)PS)], crystallizes with two practically undistiguishable mol­ecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1′-diyl units exhibit a regular geometry with negligible tilting and balanced Fe–ring centroid distances, and with the attached substituents assuming conformations close to ideal synclinal eclipsed.
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spelling pubmed-29701712010-12-30 1-Bromo-1′-(diphenyl­thio­phosphor­yl)­ferrocene Štěpnička, Petr Schulz, Jiří Císařová, Ivana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(4)Br)(C(17)H(14)PS)], crystallizes with two practically undistiguishable mol­ecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1′-diyl units exhibit a regular geometry with negligible tilting and balanced Fe–ring centroid distances, and with the attached substituents assuming conformations close to ideal synclinal eclipsed. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970171/ /pubmed/21577736 http://dx.doi.org/10.1107/S1600536809036459 Text en © Štěpnička et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Štěpnička, Petr
Schulz, Jiří
Císařová, Ivana
1-Bromo-1′-(diphenyl­thio­phosphor­yl)­ferrocene
title 1-Bromo-1′-(diphenyl­thio­phosphor­yl)­ferrocene
title_full 1-Bromo-1′-(diphenyl­thio­phosphor­yl)­ferrocene
title_fullStr 1-Bromo-1′-(diphenyl­thio­phosphor­yl)­ferrocene
title_full_unstemmed 1-Bromo-1′-(diphenyl­thio­phosphor­yl)­ferrocene
title_short 1-Bromo-1′-(diphenyl­thio­phosphor­yl)­ferrocene
title_sort 1-bromo-1′-(diphenyl­thio­phosphor­yl)­ferrocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970171/
https://www.ncbi.nlm.nih.gov/pubmed/21577736
http://dx.doi.org/10.1107/S1600536809036459
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AT schulzjiri 1bromo1diphenylthiophosphorylferrocene
AT cisarovaivana 1bromo1diphenylthiophosphorylferrocene

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