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6-Hydroxy­salvinolone

The title compound {systematic name: 5,6,10-trihydr­oxy-7-iso­propyl-1,1,4a-trimethyl-2,3,4,4a-tetra­hydro­phenanthren-9(1H)-one}, C(20)H(26)O(4), is a diterpenoid which was isolated from the roots of Premna obtusifolia. The mol­ecule has three fused six-membered rings; the cyclo­hexane ring is in a...

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Detalles Bibliográficos
Autores principales: Salae, Abdul Wahab, Chantrapromma, Suchada, Fun, Hoong-Kun, Karalai, Chatchanok
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970173/
https://www.ncbi.nlm.nih.gov/pubmed/21577844
http://dx.doi.org/10.1107/S1600536809034990
Descripción
Sumario:The title compound {systematic name: 5,6,10-trihydr­oxy-7-iso­propyl-1,1,4a-trimethyl-2,3,4,4a-tetra­hydro­phenanthren-9(1H)-one}, C(20)H(26)O(4), is a diterpenoid which was isolated from the roots of Premna obtusifolia. The mol­ecule has three fused six-membered rings; the cyclo­hexane ring is in a twisted-boat conformation and the cyclo­hexene ring adopts a sofa form. Intra­molecular O—H⋯O hydrogen bonds generate two S(5) ring motifs. In the crystal, mol­ecules are linked into infinite one-dimensional chains along the [001] direction by O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions.