6-Hydroxy­salvinolone

The title compound {systematic name: 5,6,10-trihydr­oxy-7-iso­propyl-1,1,4a-trimethyl-2,3,4,4a-tetra­hydro­phenanthren-9(1H)-one}, C(20)H(26)O(4), is a diterpenoid which was isolated from the roots of Premna obtusifolia. The mol­ecule has three fused six-membered rings; the cyclo­hexane ring is in a...

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Autores principales: Salae, Abdul Wahab, Chantrapromma, Suchada, Fun, Hoong-Kun, Karalai, Chatchanok
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970173/
https://www.ncbi.nlm.nih.gov/pubmed/21577844
http://dx.doi.org/10.1107/S1600536809034990
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author Salae, Abdul Wahab
Chantrapromma, Suchada
Fun, Hoong-Kun
Karalai, Chatchanok
author_facet Salae, Abdul Wahab
Chantrapromma, Suchada
Fun, Hoong-Kun
Karalai, Chatchanok
author_sort Salae, Abdul Wahab
collection PubMed
description The title compound {systematic name: 5,6,10-trihydr­oxy-7-iso­propyl-1,1,4a-trimethyl-2,3,4,4a-tetra­hydro­phenanthren-9(1H)-one}, C(20)H(26)O(4), is a diterpenoid which was isolated from the roots of Premna obtusifolia. The mol­ecule has three fused six-membered rings; the cyclo­hexane ring is in a twisted-boat conformation and the cyclo­hexene ring adopts a sofa form. Intra­molecular O—H⋯O hydrogen bonds generate two S(5) ring motifs. In the crystal, mol­ecules are linked into infinite one-dimensional chains along the [001] direction by O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions.
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spelling pubmed-29701732010-12-30 6-Hydroxy­salvinolone Salae, Abdul Wahab Chantrapromma, Suchada Fun, Hoong-Kun Karalai, Chatchanok Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound {systematic name: 5,6,10-trihydr­oxy-7-iso­propyl-1,1,4a-trimethyl-2,3,4,4a-tetra­hydro­phenanthren-9(1H)-one}, C(20)H(26)O(4), is a diterpenoid which was isolated from the roots of Premna obtusifolia. The mol­ecule has three fused six-membered rings; the cyclo­hexane ring is in a twisted-boat conformation and the cyclo­hexene ring adopts a sofa form. Intra­molecular O—H⋯O hydrogen bonds generate two S(5) ring motifs. In the crystal, mol­ecules are linked into infinite one-dimensional chains along the [001] direction by O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970173/ /pubmed/21577844 http://dx.doi.org/10.1107/S1600536809034990 Text en © Salae et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Salae, Abdul Wahab
Chantrapromma, Suchada
Fun, Hoong-Kun
Karalai, Chatchanok
6-Hydroxy­salvinolone
title 6-Hydroxy­salvinolone
title_full 6-Hydroxy­salvinolone
title_fullStr 6-Hydroxy­salvinolone
title_full_unstemmed 6-Hydroxy­salvinolone
title_short 6-Hydroxy­salvinolone
title_sort 6-hydroxy­salvinolone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970173/
https://www.ncbi.nlm.nih.gov/pubmed/21577844
http://dx.doi.org/10.1107/S1600536809034990
work_keys_str_mv AT salaeabdulwahab 6hydroxysalvinolone
AT chantraprommasuchada 6hydroxysalvinolone
AT funhoongkun 6hydroxysalvinolone
AT karalaichatchanok 6hydroxysalvinolone

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