catena-Poly[calcium-bis­[μ-N-(dimethyl­phosphino­yl)benzene­sulfonamidato]]

The crystal structure of the title calcium complex, [Ca(C(8)H(11)NO(5)PS)(2)](n), is composed of a polymeric chain, which is formed due to two bridging sulfonyl groups linking Ca(II) ions in a O—S—O—Ca manner. Thus, the coordination environment of the Ca(II) ions is composed of six O atoms belonging...

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Detalles Bibliográficos
Autores principales: Trush, Elizaveta A., Trush, Victor A., Sliva, Tetyana Yu., Konovalova, Irina S., Amirkhanov, Volodymyr M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970174/
https://www.ncbi.nlm.nih.gov/pubmed/21577750
http://dx.doi.org/10.1107/S1600536809032875
Descripción
Sumario:The crystal structure of the title calcium complex, [Ca(C(8)H(11)NO(5)PS)(2)](n), is composed of a polymeric chain, which is formed due to two bridging sulfonyl groups linking Ca(II) ions in a O—S—O—Ca manner. Thus, the coordination environment of the Ca(II) ions is composed of six O atoms belonging to the phosphoryl and sulfonyl groups of two chelate rings and two additional O atoms of two bridging sulfonyl groups. The coordination polyhedron of the central atom (2 symmetry) has a distorted octa­hedral geometry.

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