catena-Poly[calcium-bis­[μ-N-(dimethyl­phosphino­yl)benzene­sulfonamidato]]

The crystal structure of the title calcium complex, [Ca(C(8)H(11)NO(5)PS)(2)](n), is composed of a polymeric chain, which is formed due to two bridging sulfonyl groups linking Ca(II) ions in a O—S—O—Ca manner. Thus, the coordination environment of the Ca(II) ions is composed of six O atoms belonging...

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Detalles Bibliográficos
Autores principales: Trush, Elizaveta A., Trush, Victor A., Sliva, Tetyana Yu., Konovalova, Irina S., Amirkhanov, Volodymyr M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970174/
https://www.ncbi.nlm.nih.gov/pubmed/21577750
http://dx.doi.org/10.1107/S1600536809032875
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author Trush, Elizaveta A.
Trush, Victor A.
Sliva, Tetyana Yu.
Konovalova, Irina S.
Amirkhanov, Volodymyr M.
author_facet Trush, Elizaveta A.
Trush, Victor A.
Sliva, Tetyana Yu.
Konovalova, Irina S.
Amirkhanov, Volodymyr M.
author_sort Trush, Elizaveta A.
collection PubMed
description The crystal structure of the title calcium complex, [Ca(C(8)H(11)NO(5)PS)(2)](n), is composed of a polymeric chain, which is formed due to two bridging sulfonyl groups linking Ca(II) ions in a O—S—O—Ca manner. Thus, the coordination environment of the Ca(II) ions is composed of six O atoms belonging to the phosphoryl and sulfonyl groups of two chelate rings and two additional O atoms of two bridging sulfonyl groups. The coordination polyhedron of the central atom (2 symmetry) has a distorted octa­hedral geometry.
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spelling pubmed-29701742010-12-30 catena-Poly[calcium-bis­[μ-N-(dimethyl­phosphino­yl)benzene­sulfonamidato]] Trush, Elizaveta A. Trush, Victor A. Sliva, Tetyana Yu. Konovalova, Irina S. Amirkhanov, Volodymyr M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title calcium complex, [Ca(C(8)H(11)NO(5)PS)(2)](n), is composed of a polymeric chain, which is formed due to two bridging sulfonyl groups linking Ca(II) ions in a O—S—O—Ca manner. Thus, the coordination environment of the Ca(II) ions is composed of six O atoms belonging to the phosphoryl and sulfonyl groups of two chelate rings and two additional O atoms of two bridging sulfonyl groups. The coordination polyhedron of the central atom (2 symmetry) has a distorted octa­hedral geometry. International Union of Crystallography 2009-09-19 /pmc/articles/PMC2970174/ /pubmed/21577750 http://dx.doi.org/10.1107/S1600536809032875 Text en © Trush et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Trush, Elizaveta A.
Trush, Victor A.
Sliva, Tetyana Yu.
Konovalova, Irina S.
Amirkhanov, Volodymyr M.
catena-Poly[calcium-bis­[μ-N-(dimethyl­phosphino­yl)benzene­sulfonamidato]]
title catena-Poly[calcium-bis­[μ-N-(dimethyl­phosphino­yl)benzene­sulfonamidato]]
title_full catena-Poly[calcium-bis­[μ-N-(dimethyl­phosphino­yl)benzene­sulfonamidato]]
title_fullStr catena-Poly[calcium-bis­[μ-N-(dimethyl­phosphino­yl)benzene­sulfonamidato]]
title_full_unstemmed catena-Poly[calcium-bis­[μ-N-(dimethyl­phosphino­yl)benzene­sulfonamidato]]
title_short catena-Poly[calcium-bis­[μ-N-(dimethyl­phosphino­yl)benzene­sulfonamidato]]
title_sort catena-poly[calcium-bis­[μ-n-(dimethyl­phosphino­yl)benzene­sulfonamidato]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970174/
https://www.ncbi.nlm.nih.gov/pubmed/21577750
http://dx.doi.org/10.1107/S1600536809032875
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