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Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)]

In the title compound, [Lu(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), the Lu(3+) cations are each coordinated by eight O atoms of four terephthalate anions, one oxalate anion and one aqua ligand to complete a distorted square-anti­prismatic geometry. They are bridged by the terephthalate ligands,...

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Detalles Bibliográficos
Autores principales: Li, Zhi-Feng, Wang, Chun-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970178/
https://www.ncbi.nlm.nih.gov/pubmed/21577697
http://dx.doi.org/10.1107/S1600536809034370
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author Li, Zhi-Feng
Wang, Chun-Xiang
author_facet Li, Zhi-Feng
Wang, Chun-Xiang
author_sort Li, Zhi-Feng
collection PubMed
description In the title compound, [Lu(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), the Lu(3+) cations are each coordinated by eight O atoms of four terephthalate anions, one oxalate anion and one aqua ligand to complete a distorted square-anti­prismatic geometry. They are bridged by the terephthalate ligands, generating a three-dimensional framework, which is further stabilized by the oxalate ligands. The terephthalate ions and oxalate ions are all located on centers of inversion.
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spelling pubmed-29701782010-12-30 Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)] Li, Zhi-Feng Wang, Chun-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Lu(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), the Lu(3+) cations are each coordinated by eight O atoms of four terephthalate anions, one oxalate anion and one aqua ligand to complete a distorted square-anti­prismatic geometry. They are bridged by the terephthalate ligands, generating a three-dimensional framework, which is further stabilized by the oxalate ligands. The terephthalate ions and oxalate ions are all located on centers of inversion. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970178/ /pubmed/21577697 http://dx.doi.org/10.1107/S1600536809034370 Text en © Li and Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Zhi-Feng
Wang, Chun-Xiang
Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)]
title Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)]
title_full Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)]
title_fullStr Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)]
title_full_unstemmed Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)]
title_short Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)]
title_sort poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970178/
https://www.ncbi.nlm.nih.gov/pubmed/21577697
http://dx.doi.org/10.1107/S1600536809034370
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