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Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)]
In the title compound, [Lu(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), the Lu(3+) cations are each coordinated by eight O atoms of four terephthalate anions, one oxalate anion and one aqua ligand to complete a distorted square-antiprismatic geometry. They are bridged by the terephthalate ligands,...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970178/ https://www.ncbi.nlm.nih.gov/pubmed/21577697 http://dx.doi.org/10.1107/S1600536809034370 |
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author | Li, Zhi-Feng Wang, Chun-Xiang |
author_facet | Li, Zhi-Feng Wang, Chun-Xiang |
author_sort | Li, Zhi-Feng |
collection | PubMed |
description | In the title compound, [Lu(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), the Lu(3+) cations are each coordinated by eight O atoms of four terephthalate anions, one oxalate anion and one aqua ligand to complete a distorted square-antiprismatic geometry. They are bridged by the terephthalate ligands, generating a three-dimensional framework, which is further stabilized by the oxalate ligands. The terephthalate ions and oxalate ions are all located on centers of inversion. |
format | Text |
id | pubmed-2970178 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29701782010-12-30 Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)] Li, Zhi-Feng Wang, Chun-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Lu(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), the Lu(3+) cations are each coordinated by eight O atoms of four terephthalate anions, one oxalate anion and one aqua ligand to complete a distorted square-antiprismatic geometry. They are bridged by the terephthalate ligands, generating a three-dimensional framework, which is further stabilized by the oxalate ligands. The terephthalate ions and oxalate ions are all located on centers of inversion. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970178/ /pubmed/21577697 http://dx.doi.org/10.1107/S1600536809034370 Text en © Li and Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Zhi-Feng Wang, Chun-Xiang Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)] |
title | Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)] |
title_full | Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)] |
title_fullStr | Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)] |
title_full_unstemmed | Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)] |
title_short | Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)] |
title_sort | poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970178/ https://www.ncbi.nlm.nih.gov/pubmed/21577697 http://dx.doi.org/10.1107/S1600536809034370 |
work_keys_str_mv | AT lizhifeng polydiaquam2oxalatodim4terephthalatodilutetiumiii AT wangchunxiang polydiaquam2oxalatodim4terephthalatodilutetiumiii |