3,4-O-Isopropyl­idene-2,7-di-O-p-tolyl­sulfonyl-α-l-xylo-3-heptulo-3,6-furan­osononitrile

In the title compound, C(24)H(27)NO(10)S(2), derived from l-sorbofuran­ose, the fused five-membered rings display envelope conformations. The two tosyl­ate branches are in equatorial positions with respect to the furan­ose ring, while the hydr­oxy group is in the axial position. In the crystal struc...

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Detalles Bibliográficos
Autores principales: Ma, Liang, Li, Yun-Feng, Meng, Xiang-Bao, Li, Zhong-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970183/
https://www.ncbi.nlm.nih.gov/pubmed/21577893
http://dx.doi.org/10.1107/S1600536809032565
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author Ma, Liang
Li, Yun-Feng
Meng, Xiang-Bao
Li, Zhong-Jun
author_facet Ma, Liang
Li, Yun-Feng
Meng, Xiang-Bao
Li, Zhong-Jun
author_sort Ma, Liang
collection PubMed
description In the title compound, C(24)H(27)NO(10)S(2), derived from l-sorbofuran­ose, the fused five-membered rings display envelope conformations. The two tosyl­ate branches are in equatorial positions with respect to the furan­ose ring, while the hydr­oxy group is in the axial position. In the crystal structure, the hydr­oxy group is involved in inter­molecular O—H⋯O hydrogen bonds, linking mol­ecules in chains along [100].
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spelling pubmed-29701832010-12-30 3,4-O-Isopropyl­idene-2,7-di-O-p-tolyl­sulfonyl-α-l-xylo-3-heptulo-3,6-furan­osononitrile Ma, Liang Li, Yun-Feng Meng, Xiang-Bao Li, Zhong-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(27)NO(10)S(2), derived from l-sorbofuran­ose, the fused five-membered rings display envelope conformations. The two tosyl­ate branches are in equatorial positions with respect to the furan­ose ring, while the hydr­oxy group is in the axial position. In the crystal structure, the hydr­oxy group is involved in inter­molecular O—H⋯O hydrogen bonds, linking mol­ecules in chains along [100]. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970183/ /pubmed/21577893 http://dx.doi.org/10.1107/S1600536809032565 Text en © Ma et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ma, Liang
Li, Yun-Feng
Meng, Xiang-Bao
Li, Zhong-Jun
3,4-O-Isopropyl­idene-2,7-di-O-p-tolyl­sulfonyl-α-l-xylo-3-heptulo-3,6-furan­osononitrile
title 3,4-O-Isopropyl­idene-2,7-di-O-p-tolyl­sulfonyl-α-l-xylo-3-heptulo-3,6-furan­osononitrile
title_full 3,4-O-Isopropyl­idene-2,7-di-O-p-tolyl­sulfonyl-α-l-xylo-3-heptulo-3,6-furan­osononitrile
title_fullStr 3,4-O-Isopropyl­idene-2,7-di-O-p-tolyl­sulfonyl-α-l-xylo-3-heptulo-3,6-furan­osononitrile
title_full_unstemmed 3,4-O-Isopropyl­idene-2,7-di-O-p-tolyl­sulfonyl-α-l-xylo-3-heptulo-3,6-furan­osononitrile
title_short 3,4-O-Isopropyl­idene-2,7-di-O-p-tolyl­sulfonyl-α-l-xylo-3-heptulo-3,6-furan­osononitrile
title_sort 3,4-o-isopropyl­idene-2,7-di-o-p-tolyl­sulfonyl-α-l-xylo-3-heptulo-3,6-furan­osononitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970183/
https://www.ncbi.nlm.nih.gov/pubmed/21577893
http://dx.doi.org/10.1107/S1600536809032565
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AT mengxiangbao 34oisopropylidene27dioptolylsulfonylalxylo3heptulo36furanosononitrile
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