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1,3,5-Tris(N-phenylbenzimidazol-2-yl)benzene methanol solvate
The main molecule of the title compound, C(45)H(30)N(6)·CH(3)OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19 (10), 34.57 (8), and 44.59 (8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimid...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970194/ https://www.ncbi.nlm.nih.gov/pubmed/21577916 http://dx.doi.org/10.1107/S1600536809036046 |
Sumario: | The main molecule of the title compound, C(45)H(30)N(6)·CH(3)OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19 (10), 34.57 (8), and 44.59 (8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimidazole rings are 84.57 (7), 62.71 (6) and 51.73 (6)°. The tri-substituted benzene molecule is connected to the methanol solvent molecule through an O—H⋯N hydrogen bond, forming a 1:1 solvate. In the crystal structure, no significant π–π interactions are present, and the molecules are associated through weak C—H⋯N and C—H⋯O(methanol) contacts. |
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