Cargando…

1,3,5-Tris(N-phenyl­benzimidazol-2-yl)benzene methanol solvate

The main mol­ecule of the title compound, C(45)H(30)N(6)·CH(3)OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19 (10), 34.57 (8), and 44.59 (8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimid...

Descripción completa

Detalles Bibliográficos
Autores principales: Song, Wei-Feng, Wu, Ying, Fan, Yan, Wang, Yue, Liu, Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970194/
https://www.ncbi.nlm.nih.gov/pubmed/21577916
http://dx.doi.org/10.1107/S1600536809036046
Descripción
Sumario:The main mol­ecule of the title compound, C(45)H(30)N(6)·CH(3)OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19 (10), 34.57 (8), and 44.59 (8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimidazole rings are 84.57 (7), 62.71 (6) and 51.73 (6)°. The tri-substituted benzene mol­ecule is connected to the methanol solvent mol­ecule through an O—H⋯N hydrogen bond, forming a 1:1 solvate. In the crystal structure, no significant π–π inter­actions are present, and the mol­ecules are associated through weak C—H⋯N and C—H⋯O(methanol) contacts.