1,3,5-Tris(N-phenyl­benzimidazol-2-yl)benzene methanol solvate

The main mol­ecule of the title compound, C(45)H(30)N(6)·CH(3)OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19 (10), 34.57 (8), and 44.59 (8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimid...

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Detalles Bibliográficos
Autores principales: Song, Wei-Feng, Wu, Ying, Fan, Yan, Wang, Yue, Liu, Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970194/
https://www.ncbi.nlm.nih.gov/pubmed/21577916
http://dx.doi.org/10.1107/S1600536809036046
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author Song, Wei-Feng
Wu, Ying
Fan, Yan
Wang, Yue
Liu, Yu
author_facet Song, Wei-Feng
Wu, Ying
Fan, Yan
Wang, Yue
Liu, Yu
author_sort Song, Wei-Feng
collection PubMed
description The main mol­ecule of the title compound, C(45)H(30)N(6)·CH(3)OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19 (10), 34.57 (8), and 44.59 (8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimidazole rings are 84.57 (7), 62.71 (6) and 51.73 (6)°. The tri-substituted benzene mol­ecule is connected to the methanol solvent mol­ecule through an O—H⋯N hydrogen bond, forming a 1:1 solvate. In the crystal structure, no significant π–π inter­actions are present, and the mol­ecules are associated through weak C—H⋯N and C—H⋯O(methanol) contacts.
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spelling pubmed-29701942010-12-30 1,3,5-Tris(N-phenyl­benzimidazol-2-yl)benzene methanol solvate Song, Wei-Feng Wu, Ying Fan, Yan Wang, Yue Liu, Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers The main mol­ecule of the title compound, C(45)H(30)N(6)·CH(3)OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19 (10), 34.57 (8), and 44.59 (8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimidazole rings are 84.57 (7), 62.71 (6) and 51.73 (6)°. The tri-substituted benzene mol­ecule is connected to the methanol solvent mol­ecule through an O—H⋯N hydrogen bond, forming a 1:1 solvate. In the crystal structure, no significant π–π inter­actions are present, and the mol­ecules are associated through weak C—H⋯N and C—H⋯O(methanol) contacts. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970194/ /pubmed/21577916 http://dx.doi.org/10.1107/S1600536809036046 Text en © Song et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Song, Wei-Feng
Wu, Ying
Fan, Yan
Wang, Yue
Liu, Yu
1,3,5-Tris(N-phenyl­benzimidazol-2-yl)benzene methanol solvate
title 1,3,5-Tris(N-phenyl­benzimidazol-2-yl)benzene methanol solvate
title_full 1,3,5-Tris(N-phenyl­benzimidazol-2-yl)benzene methanol solvate
title_fullStr 1,3,5-Tris(N-phenyl­benzimidazol-2-yl)benzene methanol solvate
title_full_unstemmed 1,3,5-Tris(N-phenyl­benzimidazol-2-yl)benzene methanol solvate
title_short 1,3,5-Tris(N-phenyl­benzimidazol-2-yl)benzene methanol solvate
title_sort 1,3,5-tris(n-phenyl­benzimidazol-2-yl)benzene methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970194/
https://www.ncbi.nlm.nih.gov/pubmed/21577916
http://dx.doi.org/10.1107/S1600536809036046
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