(2E)-2-Hydroxy­imino-N′-[(E)-2-pyridyl­methyl­ene]propanohydrazide

In the title compound, C(9)H(10)N(4)O(2), the pyridine ring is twisted by 16.5 (1)° from the mean plane defined by the remaining non-H atoms. An intra­molecular N—H⋯N inter­action is present. In the crystal, inter­molecular O—H⋯N and N—H⋯O hydrogen bonds link mol­ecules into layers parallel to the b...

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Autores principales: Moroz, Yurii S., Kalibabchuk, Valentina A., Gumienna-Kontecka, Elżbieta, Skopenko, Viktor V., Pavlova, Svetlana V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970200/
https://www.ncbi.nlm.nih.gov/pubmed/21577872
http://dx.doi.org/10.1107/S1600536809034400
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author Moroz, Yurii S.
Kalibabchuk, Valentina A.
Gumienna-Kontecka, Elżbieta
Skopenko, Viktor V.
Pavlova, Svetlana V.
author_facet Moroz, Yurii S.
Kalibabchuk, Valentina A.
Gumienna-Kontecka, Elżbieta
Skopenko, Viktor V.
Pavlova, Svetlana V.
author_sort Moroz, Yurii S.
collection PubMed
description In the title compound, C(9)H(10)N(4)O(2), the pyridine ring is twisted by 16.5 (1)° from the mean plane defined by the remaining non-H atoms. An intra­molecular N—H⋯N inter­action is present. In the crystal, inter­molecular O—H⋯N and N—H⋯O hydrogen bonds link mol­ecules into layers parallel to the bc plane. The crystal packing exhibits π–π inter­actions indicated by the short distance of 3.649 (1) Å between the centroids of the pyridine rings of neighbouring mol­ecules.
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spelling pubmed-29702002010-12-30 (2E)-2-Hydroxy­imino-N′-[(E)-2-pyridyl­methyl­ene]propanohydrazide Moroz, Yurii S. Kalibabchuk, Valentina A. Gumienna-Kontecka, Elżbieta Skopenko, Viktor V. Pavlova, Svetlana V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(10)N(4)O(2), the pyridine ring is twisted by 16.5 (1)° from the mean plane defined by the remaining non-H atoms. An intra­molecular N—H⋯N inter­action is present. In the crystal, inter­molecular O—H⋯N and N—H⋯O hydrogen bonds link mol­ecules into layers parallel to the bc plane. The crystal packing exhibits π–π inter­actions indicated by the short distance of 3.649 (1) Å between the centroids of the pyridine rings of neighbouring mol­ecules. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970200/ /pubmed/21577872 http://dx.doi.org/10.1107/S1600536809034400 Text en © Moroz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moroz, Yurii S.
Kalibabchuk, Valentina A.
Gumienna-Kontecka, Elżbieta
Skopenko, Viktor V.
Pavlova, Svetlana V.
(2E)-2-Hydroxy­imino-N′-[(E)-2-pyridyl­methyl­ene]propanohydrazide
title (2E)-2-Hydroxy­imino-N′-[(E)-2-pyridyl­methyl­ene]propanohydrazide
title_full (2E)-2-Hydroxy­imino-N′-[(E)-2-pyridyl­methyl­ene]propanohydrazide
title_fullStr (2E)-2-Hydroxy­imino-N′-[(E)-2-pyridyl­methyl­ene]propanohydrazide
title_full_unstemmed (2E)-2-Hydroxy­imino-N′-[(E)-2-pyridyl­methyl­ene]propanohydrazide
title_short (2E)-2-Hydroxy­imino-N′-[(E)-2-pyridyl­methyl­ene]propanohydrazide
title_sort (2e)-2-hydroxy­imino-n′-[(e)-2-pyridyl­methyl­ene]propanohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970200/
https://www.ncbi.nlm.nih.gov/pubmed/21577872
http://dx.doi.org/10.1107/S1600536809034400
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