{2-[(2,6-Difluoro­phen­oxy)meth­yl]phen­yl}boronic acid

The planes of the two benzene rings in the mol­ecule of the title compound, C(13)H(11)BF(2)O(3), form a dihedral angle of 76.06 (3)°; the C—O—C—C torsion angle characterizing the conformation of the central link of the mol­ecule is −79.20 (1)°. The dihydroxy­boron group is not coplanar with the benz...

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Detalles Bibliográficos
Autores principales: Klis, Tomasz, Serwatowski, Janusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970217/
https://www.ncbi.nlm.nih.gov/pubmed/21577817
http://dx.doi.org/10.1107/S1600536809035235
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author Klis, Tomasz
Serwatowski, Janusz
author_facet Klis, Tomasz
Serwatowski, Janusz
author_sort Klis, Tomasz
collection PubMed
description The planes of the two benzene rings in the mol­ecule of the title compound, C(13)H(11)BF(2)O(3), form a dihedral angle of 76.06 (3)°; the C—O—C—C torsion angle characterizing the conformation of the central link of the mol­ecule is −79.20 (1)°. The dihydroxy­boron group is not coplanar with the benzene ring bonded to the B atom; one of the C—C—B—O torsion angles is 32.39 (2)°. One of the OH groups of the boronic acid fragment is engaged in an intra­molecular hydrogen bond, whereas the second OH group participates in inter­molecular hydrogen bonding, which leads to the formation of centrosymmetric dimers.
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spelling pubmed-29702172010-12-30 {2-[(2,6-Difluoro­phen­oxy)meth­yl]phen­yl}boronic acid Klis, Tomasz Serwatowski, Janusz Acta Crystallogr Sect E Struct Rep Online Organic Papers The planes of the two benzene rings in the mol­ecule of the title compound, C(13)H(11)BF(2)O(3), form a dihedral angle of 76.06 (3)°; the C—O—C—C torsion angle characterizing the conformation of the central link of the mol­ecule is −79.20 (1)°. The dihydroxy­boron group is not coplanar with the benzene ring bonded to the B atom; one of the C—C—B—O torsion angles is 32.39 (2)°. One of the OH groups of the boronic acid fragment is engaged in an intra­molecular hydrogen bond, whereas the second OH group participates in inter­molecular hydrogen bonding, which leads to the formation of centrosymmetric dimers. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970217/ /pubmed/21577817 http://dx.doi.org/10.1107/S1600536809035235 Text en © Klis and Serwatowski 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Klis, Tomasz
Serwatowski, Janusz
{2-[(2,6-Difluoro­phen­oxy)meth­yl]phen­yl}boronic acid
title {2-[(2,6-Difluoro­phen­oxy)meth­yl]phen­yl}boronic acid
title_full {2-[(2,6-Difluoro­phen­oxy)meth­yl]phen­yl}boronic acid
title_fullStr {2-[(2,6-Difluoro­phen­oxy)meth­yl]phen­yl}boronic acid
title_full_unstemmed {2-[(2,6-Difluoro­phen­oxy)meth­yl]phen­yl}boronic acid
title_short {2-[(2,6-Difluoro­phen­oxy)meth­yl]phen­yl}boronic acid
title_sort {2-[(2,6-difluoro­phen­oxy)meth­yl]phen­yl}boronic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970217/
https://www.ncbi.nlm.nih.gov/pubmed/21577817
http://dx.doi.org/10.1107/S1600536809035235
work_keys_str_mv AT klistomasz 226difluorophenoxymethylphenylboronicacid
AT serwatowskijanusz 226difluorophenoxymethylphenylboronicacid

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