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Bis[1,3-bis­(2-cyano­phen­yl)triazenido]mercury(II)

In the title compound, [Hg(C(14)H(8)N(5))(2)], the central atom is four-coordinated by two bidentate 1,3-bis­(2-cyano­phen­yl)triazenide ligands in a distorted square-planar geometry. The asymmteric unit is composed of one ligand molecule and one Hg(II) ion, which is disordered over two sites, one l...

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Autores principales: Rofouei, Mohammad Kazem, Barghamadi, Marzieh, Taghdiri, Mehdi, Attar Gharamaleki, Jafar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970218/
https://www.ncbi.nlm.nih.gov/pubmed/21577719
http://dx.doi.org/10.1107/S1600536809035326
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author Rofouei, Mohammad Kazem
Barghamadi, Marzieh
Taghdiri, Mehdi
Attar Gharamaleki, Jafar
author_facet Rofouei, Mohammad Kazem
Barghamadi, Marzieh
Taghdiri, Mehdi
Attar Gharamaleki, Jafar
author_sort Rofouei, Mohammad Kazem
collection PubMed
description In the title compound, [Hg(C(14)H(8)N(5))(2)], the central atom is four-coordinated by two bidentate 1,3-bis­(2-cyano­phen­yl)triazenide ligands in a distorted square-planar geometry. The asymmteric unit is composed of one ligand molecule and one Hg(II) ion, which is disordered over two sites, one lying on an inversion center and the other on a general position with site-occupancy factors of 0.2378 (7) and 0.3811 (7), respectively. The monomeric mol­ecules of the complex are linked into pairs through non-classical C—H⋯N hydrogen bonds. The resulting dimeric units are assembled by translation along the crystallographic c axis into chains linked through secondary π–π inter­actions [centroid–centroid distances = 3.685 (2) and 3.574 (2) Å], as well as C—H⋯π stacking inter­actions, resulting in a two-dimensional architecture.
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spelling pubmed-29702182010-12-30 Bis[1,3-bis­(2-cyano­phen­yl)triazenido]mercury(II) Rofouei, Mohammad Kazem Barghamadi, Marzieh Taghdiri, Mehdi Attar Gharamaleki, Jafar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hg(C(14)H(8)N(5))(2)], the central atom is four-coordinated by two bidentate 1,3-bis­(2-cyano­phen­yl)triazenide ligands in a distorted square-planar geometry. The asymmteric unit is composed of one ligand molecule and one Hg(II) ion, which is disordered over two sites, one lying on an inversion center and the other on a general position with site-occupancy factors of 0.2378 (7) and 0.3811 (7), respectively. The monomeric mol­ecules of the complex are linked into pairs through non-classical C—H⋯N hydrogen bonds. The resulting dimeric units are assembled by translation along the crystallographic c axis into chains linked through secondary π–π inter­actions [centroid–centroid distances = 3.685 (2) and 3.574 (2) Å], as well as C—H⋯π stacking inter­actions, resulting in a two-dimensional architecture. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970218/ /pubmed/21577719 http://dx.doi.org/10.1107/S1600536809035326 Text en © Rofouei et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rofouei, Mohammad Kazem
Barghamadi, Marzieh
Taghdiri, Mehdi
Attar Gharamaleki, Jafar
Bis[1,3-bis­(2-cyano­phen­yl)triazenido]mercury(II)
title Bis[1,3-bis­(2-cyano­phen­yl)triazenido]mercury(II)
title_full Bis[1,3-bis­(2-cyano­phen­yl)triazenido]mercury(II)
title_fullStr Bis[1,3-bis­(2-cyano­phen­yl)triazenido]mercury(II)
title_full_unstemmed Bis[1,3-bis­(2-cyano­phen­yl)triazenido]mercury(II)
title_short Bis[1,3-bis­(2-cyano­phen­yl)triazenido]mercury(II)
title_sort bis[1,3-bis­(2-cyano­phen­yl)triazenido]mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970218/
https://www.ncbi.nlm.nih.gov/pubmed/21577719
http://dx.doi.org/10.1107/S1600536809035326
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