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Bis[1,3-bis(2-cyanophenyl)triazenido]mercury(II)
In the title compound, [Hg(C(14)H(8)N(5))(2)], the central atom is four-coordinated by two bidentate 1,3-bis(2-cyanophenyl)triazenide ligands in a distorted square-planar geometry. The asymmteric unit is composed of one ligand molecule and one Hg(II) ion, which is disordered over two sites, one l...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970218/ https://www.ncbi.nlm.nih.gov/pubmed/21577719 http://dx.doi.org/10.1107/S1600536809035326 |
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author | Rofouei, Mohammad Kazem Barghamadi, Marzieh Taghdiri, Mehdi Attar Gharamaleki, Jafar |
author_facet | Rofouei, Mohammad Kazem Barghamadi, Marzieh Taghdiri, Mehdi Attar Gharamaleki, Jafar |
author_sort | Rofouei, Mohammad Kazem |
collection | PubMed |
description | In the title compound, [Hg(C(14)H(8)N(5))(2)], the central atom is four-coordinated by two bidentate 1,3-bis(2-cyanophenyl)triazenide ligands in a distorted square-planar geometry. The asymmteric unit is composed of one ligand molecule and one Hg(II) ion, which is disordered over two sites, one lying on an inversion center and the other on a general position with site-occupancy factors of 0.2378 (7) and 0.3811 (7), respectively. The monomeric molecules of the complex are linked into pairs through non-classical C—H⋯N hydrogen bonds. The resulting dimeric units are assembled by translation along the crystallographic c axis into chains linked through secondary π–π interactions [centroid–centroid distances = 3.685 (2) and 3.574 (2) Å], as well as C—H⋯π stacking interactions, resulting in a two-dimensional architecture. |
format | Text |
id | pubmed-2970218 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29702182010-12-30 Bis[1,3-bis(2-cyanophenyl)triazenido]mercury(II) Rofouei, Mohammad Kazem Barghamadi, Marzieh Taghdiri, Mehdi Attar Gharamaleki, Jafar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hg(C(14)H(8)N(5))(2)], the central atom is four-coordinated by two bidentate 1,3-bis(2-cyanophenyl)triazenide ligands in a distorted square-planar geometry. The asymmteric unit is composed of one ligand molecule and one Hg(II) ion, which is disordered over two sites, one lying on an inversion center and the other on a general position with site-occupancy factors of 0.2378 (7) and 0.3811 (7), respectively. The monomeric molecules of the complex are linked into pairs through non-classical C—H⋯N hydrogen bonds. The resulting dimeric units are assembled by translation along the crystallographic c axis into chains linked through secondary π–π interactions [centroid–centroid distances = 3.685 (2) and 3.574 (2) Å], as well as C—H⋯π stacking interactions, resulting in a two-dimensional architecture. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970218/ /pubmed/21577719 http://dx.doi.org/10.1107/S1600536809035326 Text en © Rofouei et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Rofouei, Mohammad Kazem Barghamadi, Marzieh Taghdiri, Mehdi Attar Gharamaleki, Jafar Bis[1,3-bis(2-cyanophenyl)triazenido]mercury(II) |
title | Bis[1,3-bis(2-cyanophenyl)triazenido]mercury(II) |
title_full | Bis[1,3-bis(2-cyanophenyl)triazenido]mercury(II) |
title_fullStr | Bis[1,3-bis(2-cyanophenyl)triazenido]mercury(II) |
title_full_unstemmed | Bis[1,3-bis(2-cyanophenyl)triazenido]mercury(II) |
title_short | Bis[1,3-bis(2-cyanophenyl)triazenido]mercury(II) |
title_sort | bis[1,3-bis(2-cyanophenyl)triazenido]mercury(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970218/ https://www.ncbi.nlm.nih.gov/pubmed/21577719 http://dx.doi.org/10.1107/S1600536809035326 |
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