Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron

In the title compound, C(32)H(26)BN(5) or [(C(14)H(11)N(5))B(C(6)H(5))(3)], the B atom is approximately tetra­hedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds. The crystal structure features very weak C—H⋯π inte...

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Detalles Bibliográficos
Autores principales: Urakami, Daisuke, Inoue, Katsuya, Hayami, Shinya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970225/
https://www.ncbi.nlm.nih.gov/pubmed/21577882
http://dx.doi.org/10.1107/S1600536809036071
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author Urakami, Daisuke
Inoue, Katsuya
Hayami, Shinya
author_facet Urakami, Daisuke
Inoue, Katsuya
Hayami, Shinya
author_sort Urakami, Daisuke
collection PubMed
description In the title compound, C(32)H(26)BN(5) or [(C(14)H(11)N(5))B(C(6)H(5))(3)], the B atom is approximately tetra­hedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds. The crystal structure features very weak C—H⋯π inter­actions. The dihedral angles between the central benzene ring and the terminal rings in the heterocycle are 62.64, 73.54 and 61.60°.
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spelling pubmed-29702252010-12-30 Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron Urakami, Daisuke Inoue, Katsuya Hayami, Shinya Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(32)H(26)BN(5) or [(C(14)H(11)N(5))B(C(6)H(5))(3)], the B atom is approximately tetra­hedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds. The crystal structure features very weak C—H⋯π inter­actions. The dihedral angles between the central benzene ring and the terminal rings in the heterocycle are 62.64, 73.54 and 61.60°. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970225/ /pubmed/21577882 http://dx.doi.org/10.1107/S1600536809036071 Text en © Urakami et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Urakami, Daisuke
Inoue, Katsuya
Hayami, Shinya
Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title_full Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title_fullStr Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title_full_unstemmed Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title_short Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title_sort triphenyl{(e)-4-[4-(phenyldiazenyl)phenyl]-4h-1,2,4-triazol-1-yl}boron
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970225/
https://www.ncbi.nlm.nih.gov/pubmed/21577882
http://dx.doi.org/10.1107/S1600536809036071
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AT hayamishinya triphenyle44phenyldiazenylphenyl4h124triazol1ylboron

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