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Dibromido{2-hydr­oxy-N′-[phen­yl(2-pyrid­yl)methyl­ene]benzohydrazide}copper(II)

In the title complex, [CuBr(2)(C(19)H(15)N(3)O(2))], the metal ion is coordinated by the N,N′,O-tridentate 2-hydr­oxy-N′-[phen­yl(2-pyrid­yl)methyl­ene]benzohydrazide ligand and two bromide ions, resulting in a distorted CuN(2)OBr(2) square-based pyramidal coordination geometry with one bromide ion...

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Detalles Bibliográficos
Autores principales: Kong, Ling-Qian, Ju, Xiu-Ping, Li, Da-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970229/
https://www.ncbi.nlm.nih.gov/pubmed/21577767
http://dx.doi.org/10.1107/S1600536809038070
Descripción
Sumario:In the title complex, [CuBr(2)(C(19)H(15)N(3)O(2))], the metal ion is coordinated by the N,N′,O-tridentate 2-hydr­oxy-N′-[phen­yl(2-pyrid­yl)methyl­ene]benzohydrazide ligand and two bromide ions, resulting in a distorted CuN(2)OBr(2) square-based pyramidal coordination geometry with one bromide ion in the apical site. An intra­molecular N—H⋯O hydrogen bond occurs in the ligand. In the crystal, mol­ecules are connected by inter­molecular C—H⋯O, C—H⋯Br and O—H⋯Br inter­actions.