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Dibromido{2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(II)
In the title complex, [CuBr(2)(C(19)H(15)N(3)O(2))], the metal ion is coordinated by the N,N′,O-tridentate 2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide ligand and two bromide ions, resulting in a distorted CuN(2)OBr(2) square-based pyramidal coordination geometry with one bromide ion...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970229/ https://www.ncbi.nlm.nih.gov/pubmed/21577767 http://dx.doi.org/10.1107/S1600536809038070 |
Sumario: | In the title complex, [CuBr(2)(C(19)H(15)N(3)O(2))], the metal ion is coordinated by the N,N′,O-tridentate 2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide ligand and two bromide ions, resulting in a distorted CuN(2)OBr(2) square-based pyramidal coordination geometry with one bromide ion in the apical site. An intramolecular N—H⋯O hydrogen bond occurs in the ligand. In the crystal, molecules are connected by intermolecular C—H⋯O, C—H⋯Br and O—H⋯Br interactions. |
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