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Dibromido{2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(II)
In the title complex, [CuBr(2)(C(19)H(15)N(3)O(2))], the metal ion is coordinated by the N,N′,O-tridentate 2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide ligand and two bromide ions, resulting in a distorted CuN(2)OBr(2) square-based pyramidal coordination geometry with one bromide ion...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970229/ https://www.ncbi.nlm.nih.gov/pubmed/21577767 http://dx.doi.org/10.1107/S1600536809038070 |
| _version_ | 1782190385668292608 |
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| author | Kong, Ling-Qian Ju, Xiu-Ping Li, Da-Cheng |
| author_facet | Kong, Ling-Qian Ju, Xiu-Ping Li, Da-Cheng |
| author_sort | Kong, Ling-Qian |
| collection | PubMed |
| description | In the title complex, [CuBr(2)(C(19)H(15)N(3)O(2))], the metal ion is coordinated by the N,N′,O-tridentate 2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide ligand and two bromide ions, resulting in a distorted CuN(2)OBr(2) square-based pyramidal coordination geometry with one bromide ion in the apical site. An intramolecular N—H⋯O hydrogen bond occurs in the ligand. In the crystal, molecules are connected by intermolecular C—H⋯O, C—H⋯Br and O—H⋯Br interactions. |
| format | Text |
| id | pubmed-2970229 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29702292010-12-30 Dibromido{2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(II) Kong, Ling-Qian Ju, Xiu-Ping Li, Da-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuBr(2)(C(19)H(15)N(3)O(2))], the metal ion is coordinated by the N,N′,O-tridentate 2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide ligand and two bromide ions, resulting in a distorted CuN(2)OBr(2) square-based pyramidal coordination geometry with one bromide ion in the apical site. An intramolecular N—H⋯O hydrogen bond occurs in the ligand. In the crystal, molecules are connected by intermolecular C—H⋯O, C—H⋯Br and O—H⋯Br interactions. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970229/ /pubmed/21577767 http://dx.doi.org/10.1107/S1600536809038070 Text en © Kong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kong, Ling-Qian Ju, Xiu-Ping Li, Da-Cheng Dibromido{2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(II) |
| title | Dibromido{2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(II) |
| title_full | Dibromido{2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(II) |
| title_fullStr | Dibromido{2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(II) |
| title_full_unstemmed | Dibromido{2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(II) |
| title_short | Dibromido{2-hydroxy-N′-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(II) |
| title_sort | dibromido{2-hydroxy-n′-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970229/ https://www.ncbi.nlm.nih.gov/pubmed/21577767 http://dx.doi.org/10.1107/S1600536809038070 |
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