catena-Poly[[[diaqua­copper(II)]-bis­[μ(2)-1,3-bis­(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate]

The title Cu(II) coordination polymer, {[Cu(C(7)H(10)N(6))(2)(H(2)O)(2)](NO(3))(2)·H(2)O}(n), was obtained by the reaction of equimolar Cu(NO(3))(2)·4H(2)O and 1,3-bis­(1,2,4-triazol-1-yl)propane (btp) in a water–methanol solvent. The Cu(II) atom is located on a centre of inversion and has an elonga...

Descripción completa

Detalles Bibliográficos
Autores principales: Feng, Wen, Zhao, Xiao-Jun, Yang, En-Cui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970232/
https://www.ncbi.nlm.nih.gov/pubmed/21577727
http://dx.doi.org/10.1107/S1600536809035958
_version_ 1782190386792366080
author Feng, Wen
Zhao, Xiao-Jun
Yang, En-Cui
author_facet Feng, Wen
Zhao, Xiao-Jun
Yang, En-Cui
author_sort Feng, Wen
collection PubMed
description The title Cu(II) coordination polymer, {[Cu(C(7)H(10)N(6))(2)(H(2)O)(2)](NO(3))(2)·H(2)O}(n), was obtained by the reaction of equimolar Cu(NO(3))(2)·4H(2)O and 1,3-bis­(1,2,4-triazol-1-yl)propane (btp) in a water–methanol solvent. The Cu(II) atom is located on a centre of inversion and has an elongated octa­hedral coordination geometry formed by four N atoms from four symmetry-related btp ligands and two coordinated water mol­ecules. Adjacent Cu(II) atoms are connected by btp ligands, generating a double-stranded chain. The nitrate anion is disordered over two positions in a 0.828 (7):0.172 (2) ratio.
format Text
id pubmed-2970232
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29702322010-12-30 catena-Poly[[[diaqua­copper(II)]-bis­[μ(2)-1,3-bis­(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate] Feng, Wen Zhao, Xiao-Jun Yang, En-Cui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Cu(II) coordination polymer, {[Cu(C(7)H(10)N(6))(2)(H(2)O)(2)](NO(3))(2)·H(2)O}(n), was obtained by the reaction of equimolar Cu(NO(3))(2)·4H(2)O and 1,3-bis­(1,2,4-triazol-1-yl)propane (btp) in a water–methanol solvent. The Cu(II) atom is located on a centre of inversion and has an elongated octa­hedral coordination geometry formed by four N atoms from four symmetry-related btp ligands and two coordinated water mol­ecules. Adjacent Cu(II) atoms are connected by btp ligands, generating a double-stranded chain. The nitrate anion is disordered over two positions in a 0.828 (7):0.172 (2) ratio. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970232/ /pubmed/21577727 http://dx.doi.org/10.1107/S1600536809035958 Text en © Feng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Feng, Wen
Zhao, Xiao-Jun
Yang, En-Cui
catena-Poly[[[diaqua­copper(II)]-bis­[μ(2)-1,3-bis­(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate]
title catena-Poly[[[diaqua­copper(II)]-bis­[μ(2)-1,3-bis­(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate]
title_full catena-Poly[[[diaqua­copper(II)]-bis­[μ(2)-1,3-bis­(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate]
title_fullStr catena-Poly[[[diaqua­copper(II)]-bis­[μ(2)-1,3-bis­(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate]
title_full_unstemmed catena-Poly[[[diaqua­copper(II)]-bis­[μ(2)-1,3-bis­(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate]
title_short catena-Poly[[[diaqua­copper(II)]-bis­[μ(2)-1,3-bis­(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate]
title_sort catena-poly[[[diaqua­copper(ii)]-bis­[μ(2)-1,3-bis­(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970232/
https://www.ncbi.nlm.nih.gov/pubmed/21577727
http://dx.doi.org/10.1107/S1600536809035958
work_keys_str_mv AT fengwen catenapolydiaquacopperiibism213bis124triazol1ylpropanedinitratemonohydrate
AT zhaoxiaojun catenapolydiaquacopperiibism213bis124triazol1ylpropanedinitratemonohydrate
AT yangencui catenapolydiaquacopperiibism213bis124triazol1ylpropanedinitratemonohydrate

Ejemplares similares