Diaqua­bis[2-(4-bromo­phen­yl)acetato]bis­(N (4),N (4)-dimethyl­pyridin-4-amine)copper(II)

In the title compound, [Cu(C(8)H(6)BrO(2))(2)(C(7)H(10)N(2))(2)(H(2)O)(2)], the Cu(II) atom (site symmetry [Image: see text]) adopts a Jahn–Teller-distorted trans-CuN(2)O(4) octa­hedral coordination, with the aqua O atoms in axially extended sites. An intra­molecular O—H⋯O hydrogen bond helps to est...

Descripción completa

Detalles Bibliográficos
Autores principales: Cui, Yong-Ming, Dai, Xi-Bin, Zha, Ru-Hua, Zeng, Qing-Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970236/
https://www.ncbi.nlm.nih.gov/pubmed/21577701
http://dx.doi.org/10.1107/S1600536809034461
_version_ 1782190388044365824
author Cui, Yong-Ming
Dai, Xi-Bin
Zha, Ru-Hua
Zeng, Qing-Fu
author_facet Cui, Yong-Ming
Dai, Xi-Bin
Zha, Ru-Hua
Zeng, Qing-Fu
author_sort Cui, Yong-Ming
collection PubMed
description In the title compound, [Cu(C(8)H(6)BrO(2))(2)(C(7)H(10)N(2))(2)(H(2)O)(2)], the Cu(II) atom (site symmetry [Image: see text]) adopts a Jahn–Teller-distorted trans-CuN(2)O(4) octa­hedral coordination, with the aqua O atoms in axially extended sites. An intra­molecular O—H⋯O hydrogen bond helps to establish the conformation and an inter­molecular O—H⋯O hydrogen bond is seen in the crystal packing.
format Text
id pubmed-2970236
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29702362010-12-30 Diaqua­bis[2-(4-bromo­phen­yl)acetato]bis­(N (4),N (4)-dimethyl­pyridin-4-amine)copper(II) Cui, Yong-Ming Dai, Xi-Bin Zha, Ru-Hua Zeng, Qing-Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(6)BrO(2))(2)(C(7)H(10)N(2))(2)(H(2)O)(2)], the Cu(II) atom (site symmetry [Image: see text]) adopts a Jahn–Teller-distorted trans-CuN(2)O(4) octa­hedral coordination, with the aqua O atoms in axially extended sites. An intra­molecular O—H⋯O hydrogen bond helps to establish the conformation and an inter­molecular O—H⋯O hydrogen bond is seen in the crystal packing. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970236/ /pubmed/21577701 http://dx.doi.org/10.1107/S1600536809034461 Text en © Cui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Yong-Ming
Dai, Xi-Bin
Zha, Ru-Hua
Zeng, Qing-Fu
Diaqua­bis[2-(4-bromo­phen­yl)acetato]bis­(N (4),N (4)-dimethyl­pyridin-4-amine)copper(II)
title Diaqua­bis[2-(4-bromo­phen­yl)acetato]bis­(N (4),N (4)-dimethyl­pyridin-4-amine)copper(II)
title_full Diaqua­bis[2-(4-bromo­phen­yl)acetato]bis­(N (4),N (4)-dimethyl­pyridin-4-amine)copper(II)
title_fullStr Diaqua­bis[2-(4-bromo­phen­yl)acetato]bis­(N (4),N (4)-dimethyl­pyridin-4-amine)copper(II)
title_full_unstemmed Diaqua­bis[2-(4-bromo­phen­yl)acetato]bis­(N (4),N (4)-dimethyl­pyridin-4-amine)copper(II)
title_short Diaqua­bis[2-(4-bromo­phen­yl)acetato]bis­(N (4),N (4)-dimethyl­pyridin-4-amine)copper(II)
title_sort diaqua­bis[2-(4-bromo­phen­yl)acetato]bis­(n (4),n (4)-dimethyl­pyridin-4-amine)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970236/
https://www.ncbi.nlm.nih.gov/pubmed/21577701
http://dx.doi.org/10.1107/S1600536809034461
work_keys_str_mv AT cuiyongming diaquabis24bromophenylacetatobisn4n4dimethylpyridin4aminecopperii
AT daixibin diaquabis24bromophenylacetatobisn4n4dimethylpyridin4aminecopperii
AT zharuhua diaquabis24bromophenylacetatobisn4n4dimethylpyridin4aminecopperii
AT zengqingfu diaquabis24bromophenylacetatobisn4n4dimethylpyridin4aminecopperii

Ejemplares similares