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2,2-Dimethyl-5-(2-naphthylaminomethylene)-1,3-dioxane-4,6-dione
There are two unique molecules in the asymmetric unit of the title compound, C(17)H(15)NO(4), which are linked into chains via intermolecular N—H⋯O and C—H⋯O interactions; the chains are linked via weak C—H⋯O interactions, forming a parallel sheet structure. The molecule is approximately planar,...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970245/ https://www.ncbi.nlm.nih.gov/pubmed/21578013 http://dx.doi.org/10.1107/S1600536809038458 |
Sumario: | There are two unique molecules in the asymmetric unit of the title compound, C(17)H(15)NO(4), which are linked into chains via intermolecular N—H⋯O and C—H⋯O interactions; the chains are linked via weak C—H⋯O interactions, forming a parallel sheet structure. The molecule is approximately planar, with dihedral angles of 19.91 (4) and 11.06 (4)° between the naphthyl ring and the aminomethylene group, and between the aminomethylene unit and the planar part of the dioxane ring, respectively. The dioxane ring adopts a half-boat conformation, with the C atom between the dioxane O atoms 0.595 (8) Å out of the plane through the remaining atoms. The molecule has an intramolecular N—H⋯O hydrogen bond which stabilizes the planar conformation. |
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