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2,2-Dimethyl-5-(2-naphthylaminomethylene)-1,3-dioxane-4,6-dione
There are two unique molecules in the asymmetric unit of the title compound, C(17)H(15)NO(4), which are linked into chains via intermolecular N—H⋯O and C—H⋯O interactions; the chains are linked via weak C—H⋯O interactions, forming a parallel sheet structure. The molecule is approximately planar,...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970245/ https://www.ncbi.nlm.nih.gov/pubmed/21578013 http://dx.doi.org/10.1107/S1600536809038458 |
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author | Li, Rui Ding, Zhen-Yu |
author_facet | Li, Rui Ding, Zhen-Yu |
author_sort | Li, Rui |
collection | PubMed |
description | There are two unique molecules in the asymmetric unit of the title compound, C(17)H(15)NO(4), which are linked into chains via intermolecular N—H⋯O and C—H⋯O interactions; the chains are linked via weak C—H⋯O interactions, forming a parallel sheet structure. The molecule is approximately planar, with dihedral angles of 19.91 (4) and 11.06 (4)° between the naphthyl ring and the aminomethylene group, and between the aminomethylene unit and the planar part of the dioxane ring, respectively. The dioxane ring adopts a half-boat conformation, with the C atom between the dioxane O atoms 0.595 (8) Å out of the plane through the remaining atoms. The molecule has an intramolecular N—H⋯O hydrogen bond which stabilizes the planar conformation. |
format | Text |
id | pubmed-2970245 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29702452010-12-30 2,2-Dimethyl-5-(2-naphthylaminomethylene)-1,3-dioxane-4,6-dione Li, Rui Ding, Zhen-Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two unique molecules in the asymmetric unit of the title compound, C(17)H(15)NO(4), which are linked into chains via intermolecular N—H⋯O and C—H⋯O interactions; the chains are linked via weak C—H⋯O interactions, forming a parallel sheet structure. The molecule is approximately planar, with dihedral angles of 19.91 (4) and 11.06 (4)° between the naphthyl ring and the aminomethylene group, and between the aminomethylene unit and the planar part of the dioxane ring, respectively. The dioxane ring adopts a half-boat conformation, with the C atom between the dioxane O atoms 0.595 (8) Å out of the plane through the remaining atoms. The molecule has an intramolecular N—H⋯O hydrogen bond which stabilizes the planar conformation. International Union of Crystallography 2009-09-30 /pmc/articles/PMC2970245/ /pubmed/21578013 http://dx.doi.org/10.1107/S1600536809038458 Text en © Li and Ding 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Rui Ding, Zhen-Yu 2,2-Dimethyl-5-(2-naphthylaminomethylene)-1,3-dioxane-4,6-dione |
title | 2,2-Dimethyl-5-(2-naphthylaminomethylene)-1,3-dioxane-4,6-dione |
title_full | 2,2-Dimethyl-5-(2-naphthylaminomethylene)-1,3-dioxane-4,6-dione |
title_fullStr | 2,2-Dimethyl-5-(2-naphthylaminomethylene)-1,3-dioxane-4,6-dione |
title_full_unstemmed | 2,2-Dimethyl-5-(2-naphthylaminomethylene)-1,3-dioxane-4,6-dione |
title_short | 2,2-Dimethyl-5-(2-naphthylaminomethylene)-1,3-dioxane-4,6-dione |
title_sort | 2,2-dimethyl-5-(2-naphthylaminomethylene)-1,3-dioxane-4,6-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970245/ https://www.ncbi.nlm.nih.gov/pubmed/21578013 http://dx.doi.org/10.1107/S1600536809038458 |
work_keys_str_mv | AT lirui 22dimethyl52naphthylaminomethylene13dioxane46dione AT dingzhenyu 22dimethyl52naphthylaminomethylene13dioxane46dione |