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2,2-Dimethyl-5-(2-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione

There are two unique mol­ecules in the asymmetric unit of the title compound, C(17)H(15)NO(4), which are linked into chains via inter­molecular N—H⋯O and C—H⋯O inter­actions; the chains are linked via weak C—H⋯O inter­actions, forming a parallel sheet structure. The molecule is approximately planar,...

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Detalles Bibliográficos
Autores principales: Li, Rui, Ding, Zhen-Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970245/
https://www.ncbi.nlm.nih.gov/pubmed/21578013
http://dx.doi.org/10.1107/S1600536809038458
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author Li, Rui
Ding, Zhen-Yu
author_facet Li, Rui
Ding, Zhen-Yu
author_sort Li, Rui
collection PubMed
description There are two unique mol­ecules in the asymmetric unit of the title compound, C(17)H(15)NO(4), which are linked into chains via inter­molecular N—H⋯O and C—H⋯O inter­actions; the chains are linked via weak C—H⋯O inter­actions, forming a parallel sheet structure. The molecule is approximately planar, with dihedral angles of 19.91 (4) and 11.06 (4)° between the naphthyl ring and the amino­methyl­ene group, and between the amino­methyl­ene unit and the planar part of the dioxane ring, respectively. The dioxane ring adopts a half-boat conformation, with the C atom between the dioxane O atoms 0.595 (8) Å out of the plane through the remaining atoms. The mol­ecule has an intra­molecular N—H⋯O hydrogen bond which stabilizes the planar conformation.
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spelling pubmed-29702452010-12-30 2,2-Dimethyl-5-(2-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione Li, Rui Ding, Zhen-Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two unique mol­ecules in the asymmetric unit of the title compound, C(17)H(15)NO(4), which are linked into chains via inter­molecular N—H⋯O and C—H⋯O inter­actions; the chains are linked via weak C—H⋯O inter­actions, forming a parallel sheet structure. The molecule is approximately planar, with dihedral angles of 19.91 (4) and 11.06 (4)° between the naphthyl ring and the amino­methyl­ene group, and between the amino­methyl­ene unit and the planar part of the dioxane ring, respectively. The dioxane ring adopts a half-boat conformation, with the C atom between the dioxane O atoms 0.595 (8) Å out of the plane through the remaining atoms. The mol­ecule has an intra­molecular N—H⋯O hydrogen bond which stabilizes the planar conformation. International Union of Crystallography 2009-09-30 /pmc/articles/PMC2970245/ /pubmed/21578013 http://dx.doi.org/10.1107/S1600536809038458 Text en © Li and Ding 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Rui
Ding, Zhen-Yu
2,2-Dimethyl-5-(2-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title 2,2-Dimethyl-5-(2-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title_full 2,2-Dimethyl-5-(2-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title_fullStr 2,2-Dimethyl-5-(2-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title_full_unstemmed 2,2-Dimethyl-5-(2-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title_short 2,2-Dimethyl-5-(2-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title_sort 2,2-dimethyl-5-(2-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970245/
https://www.ncbi.nlm.nih.gov/pubmed/21578013
http://dx.doi.org/10.1107/S1600536809038458
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AT dingzhenyu 22dimethyl52naphthylaminomethylene13dioxane46dione