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Tetrakis(6-methyl-2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′;3κ(2) N,N′;4κ(2) N,N′-tetra-μ-nitrato-1:2κ(2) O:O′;2:3κ(3) O:O′,O′′;2:3κ(3) O,O′:O′′;3:4κ(2) O:O′-tetranitrato-1κ(4) O,O′;4κ(2) O,O′-tetralead(II)
In the tetranuclear centrosymmetric title compound, [Pb(4)(NO(3))(8)(C(11)H(10)N(2))(4)], irregular PbN(2)O(5) and PbN(2)O(4) coordination polyhedra occur. The heptacoordinated lead(II) ion is bonded to two bidentate and one monodentate nitrate ion and one bidentate 6-methyl-2,2′-bipyridine (mbpy)...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970246/ https://www.ncbi.nlm.nih.gov/pubmed/21577706 http://dx.doi.org/10.1107/S160053680903459X |
| _version_ | 1782190390811557888 |
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| author | Ahmadi, Roya Kalateh, Khadijeh Alizadeh, Robabeh Khoshtarkib, Zeinab Amani, Vahid |
| author_facet | Ahmadi, Roya Kalateh, Khadijeh Alizadeh, Robabeh Khoshtarkib, Zeinab Amani, Vahid |
| author_sort | Ahmadi, Roya |
| collection | PubMed |
| description | In the tetranuclear centrosymmetric title compound, [Pb(4)(NO(3))(8)(C(11)H(10)N(2))(4)], irregular PbN(2)O(5) and PbN(2)O(4) coordination polyhedra occur. The heptacoordinated lead(II) ion is bonded to two bidentate and one monodentate nitrate ion and one bidentate 6-methyl-2,2′-bipyridine (mbpy) ligand. The six-coordinate lead(II) ion is bonded to one bidentate and two monodentate nitrate anions and one mbpy ligand. In the crystal, bridging nitrate anions lead to infinite chains propagating in [111]. A number of C—H⋯O hydrogen bonds may stabilize the structure. |
| format | Text |
| id | pubmed-2970246 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29702462010-12-30 Tetrakis(6-methyl-2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′;3κ(2) N,N′;4κ(2) N,N′-tetra-μ-nitrato-1:2κ(2) O:O′;2:3κ(3) O:O′,O′′;2:3κ(3) O,O′:O′′;3:4κ(2) O:O′-tetranitrato-1κ(4) O,O′;4κ(2) O,O′-tetralead(II) Ahmadi, Roya Kalateh, Khadijeh Alizadeh, Robabeh Khoshtarkib, Zeinab Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the tetranuclear centrosymmetric title compound, [Pb(4)(NO(3))(8)(C(11)H(10)N(2))(4)], irregular PbN(2)O(5) and PbN(2)O(4) coordination polyhedra occur. The heptacoordinated lead(II) ion is bonded to two bidentate and one monodentate nitrate ion and one bidentate 6-methyl-2,2′-bipyridine (mbpy) ligand. The six-coordinate lead(II) ion is bonded to one bidentate and two monodentate nitrate anions and one mbpy ligand. In the crystal, bridging nitrate anions lead to infinite chains propagating in [111]. A number of C—H⋯O hydrogen bonds may stabilize the structure. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970246/ /pubmed/21577706 http://dx.doi.org/10.1107/S160053680903459X Text en © Ahmadi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ahmadi, Roya Kalateh, Khadijeh Alizadeh, Robabeh Khoshtarkib, Zeinab Amani, Vahid Tetrakis(6-methyl-2,2′-bipyridine)-1κ(2) N,N′;2κ(2) N,N′;3κ(2) N,N′;4κ(2) N,N′-tetra-μ-nitrato-1:2κ(2) O:O′;2:3κ(3) O:O′,O′′;2:3κ(3) O,O′:O′′;3:4κ(2) O:O′-tetranitrato-1κ(4) O,O′;4κ(2) O,O′-tetralead(II) |
| title | Tetrakis(6-methyl-2,2′-bipyridine)-1κ(2)
N,N′;2κ(2)
N,N′;3κ(2)
N,N′;4κ(2)
N,N′-tetra-μ-nitrato-1:2κ(2)
O:O′;2:3κ(3)
O:O′,O′′;2:3κ(3)
O,O′:O′′;3:4κ(2)
O:O′-tetranitrato-1κ(4)
O,O′;4κ(2)
O,O′-tetralead(II) |
| title_full | Tetrakis(6-methyl-2,2′-bipyridine)-1κ(2)
N,N′;2κ(2)
N,N′;3κ(2)
N,N′;4κ(2)
N,N′-tetra-μ-nitrato-1:2κ(2)
O:O′;2:3κ(3)
O:O′,O′′;2:3κ(3)
O,O′:O′′;3:4κ(2)
O:O′-tetranitrato-1κ(4)
O,O′;4κ(2)
O,O′-tetralead(II) |
| title_fullStr | Tetrakis(6-methyl-2,2′-bipyridine)-1κ(2)
N,N′;2κ(2)
N,N′;3κ(2)
N,N′;4κ(2)
N,N′-tetra-μ-nitrato-1:2κ(2)
O:O′;2:3κ(3)
O:O′,O′′;2:3κ(3)
O,O′:O′′;3:4κ(2)
O:O′-tetranitrato-1κ(4)
O,O′;4κ(2)
O,O′-tetralead(II) |
| title_full_unstemmed | Tetrakis(6-methyl-2,2′-bipyridine)-1κ(2)
N,N′;2κ(2)
N,N′;3κ(2)
N,N′;4κ(2)
N,N′-tetra-μ-nitrato-1:2κ(2)
O:O′;2:3κ(3)
O:O′,O′′;2:3κ(3)
O,O′:O′′;3:4κ(2)
O:O′-tetranitrato-1κ(4)
O,O′;4κ(2)
O,O′-tetralead(II) |
| title_short | Tetrakis(6-methyl-2,2′-bipyridine)-1κ(2)
N,N′;2κ(2)
N,N′;3κ(2)
N,N′;4κ(2)
N,N′-tetra-μ-nitrato-1:2κ(2)
O:O′;2:3κ(3)
O:O′,O′′;2:3κ(3)
O,O′:O′′;3:4κ(2)
O:O′-tetranitrato-1κ(4)
O,O′;4κ(2)
O,O′-tetralead(II) |
| title_sort | tetrakis(6-methyl-2,2′-bipyridine)-1κ(2)
n,n′;2κ(2)
n,n′;3κ(2)
n,n′;4κ(2)
n,n′-tetra-μ-nitrato-1:2κ(2)
o:o′;2:3κ(3)
o:o′,o′′;2:3κ(3)
o,o′:o′′;3:4κ(2)
o:o′-tetranitrato-1κ(4)
o,o′;4κ(2)
o,o′-tetralead(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970246/ https://www.ncbi.nlm.nih.gov/pubmed/21577706 http://dx.doi.org/10.1107/S160053680903459X |
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