Bis(2,2′-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate

The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio­phosgene and bis­(2,2′-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis­(hexa­fluoridophosphate). The Ru(II) atom adopts a slightly distorted octa­hedral RuN(6) coordinaton f...

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Detalles Bibliográficos
Autores principales: Nag, Samik, Pal, Amlan K., Hanan, Garry S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970250/
https://www.ncbi.nlm.nih.gov/pubmed/21577718
http://dx.doi.org/10.1107/S1600536809035302
Descripción
Sumario:The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio­phosgene and bis­(2,2′-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis­(hexa­fluoridophosphate). The Ru(II) atom adopts a slightly distorted octa­hedral RuN(6) coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothio­cyanate group is almost linear, with an N—C—S angle of 174.4 (6)°. Two of the three hexa­fluoridophosphate counter-anions are located on inversion centres.

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