Bis(2,2′-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate

The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio­phosgene and bis­(2,2′-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis­(hexa­fluoridophosphate). The Ru(II) atom adopts a slightly distorted octa­hedral RuN(6) coordinaton f...

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Detalles Bibliográficos
Autores principales: Nag, Samik, Pal, Amlan K., Hanan, Garry S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970250/
https://www.ncbi.nlm.nih.gov/pubmed/21577718
http://dx.doi.org/10.1107/S1600536809035302
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author Nag, Samik
Pal, Amlan K.
Hanan, Garry S.
author_facet Nag, Samik
Pal, Amlan K.
Hanan, Garry S.
author_sort Nag, Samik
collection PubMed
description The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio­phosgene and bis­(2,2′-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis­(hexa­fluoridophosphate). The Ru(II) atom adopts a slightly distorted octa­hedral RuN(6) coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothio­cyanate group is almost linear, with an N—C—S angle of 174.4 (6)°. Two of the three hexa­fluoridophosphate counter-anions are located on inversion centres.
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spelling pubmed-29702502010-12-30 Bis(2,2′-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate Nag, Samik Pal, Amlan K. Hanan, Garry S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio­phosgene and bis­(2,2′-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis­(hexa­fluoridophosphate). The Ru(II) atom adopts a slightly distorted octa­hedral RuN(6) coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothio­cyanate group is almost linear, with an N—C—S angle of 174.4 (6)°. Two of the three hexa­fluoridophosphate counter-anions are located on inversion centres. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970250/ /pubmed/21577718 http://dx.doi.org/10.1107/S1600536809035302 Text en © Nag et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nag, Samik
Pal, Amlan K.
Hanan, Garry S.
Bis(2,2′-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate
title Bis(2,2′-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate
title_full Bis(2,2′-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate
title_fullStr Bis(2,2′-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate
title_full_unstemmed Bis(2,2′-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate
title_short Bis(2,2′-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate
title_sort bis(2,2′-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(ii) bis­(hexa­fluoridophosphate) acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970250/
https://www.ncbi.nlm.nih.gov/pubmed/21577718
http://dx.doi.org/10.1107/S1600536809035302
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AT palamlank bis22bipyridine5isothiocyanato110phenanthrolinerutheniumiibishexafluoridophosphateacetonitrilesolvate
AT hanangarrys bis22bipyridine5isothiocyanato110phenanthrolinerutheniumiibishexafluoridophosphateacetonitrilesolvate

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