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(R,R)-(N,N′-Diferrocenylcyclohexane-1,2-diyldiimino)dibenzonitrile
In the title compound, [Fe(2)(C(5)H(5))(2)(C(34)H(34)N(4))], two ferrocenes are bridged by a cyclohexane-1,2-diamine unit. The cyclopentadienyl rings of the two ferrocene units are almost parallel [dihedral angles of 0.7 (4) and 1.0 (4)° in the two units] and eclipsed, as is typically found for s...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970254/ https://www.ncbi.nlm.nih.gov/pubmed/21577729 http://dx.doi.org/10.1107/S1600536809035788 |
Sumario: | In the title compound, [Fe(2)(C(5)H(5))(2)(C(34)H(34)N(4))], two ferrocenes are bridged by a cyclohexane-1,2-diamine unit. The cyclopentadienyl rings of the two ferrocene units are almost parallel [dihedral angles of 0.7 (4) and 1.0 (4)° in the two units] and eclipsed, as is typically found for similar monosubstituted ferrocene derivatives. The dihedral angle formed by the two benzene rings is 20.2 (3)°. The Fe—C bond lengths to the two substituted Cp rings vary from 2.014 (4) to 2.070 (3) Å, and are in the normal range. In the crystal, molecules are linked by C—H⋯N interactions, forming an infinite two-dimensional network. |
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