(R,R)-(N,N′-Diferrocenylcyclo­hexane-1,2-diyldiimino)dibenzonitrile

In the title compound, [Fe(2)(C(5)H(5))(2)(C(34)H(34)N(4))], two ferrocenes are bridged by a cyclo­hexane-1,2-diamine unit. The cyclo­penta­dienyl rings of the two ferrocene units are almost parallel [dihedral angles of 0.7 (4) and 1.0 (4)° in the two units] and eclipsed, as is typically found for s...

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Detalles Bibliográficos
Autor principal: Chen, Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970254/
https://www.ncbi.nlm.nih.gov/pubmed/21577729
http://dx.doi.org/10.1107/S1600536809035788
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author Chen, Fang
author_facet Chen, Fang
author_sort Chen, Fang
collection PubMed
description In the title compound, [Fe(2)(C(5)H(5))(2)(C(34)H(34)N(4))], two ferrocenes are bridged by a cyclo­hexane-1,2-diamine unit. The cyclo­penta­dienyl rings of the two ferrocene units are almost parallel [dihedral angles of 0.7 (4) and 1.0 (4)° in the two units] and eclipsed, as is typically found for similar monosubstituted ferrocene derivatives. The dihedral angle formed by the two benzene rings is 20.2 (3)°. The Fe—C bond lengths to the two substituted Cp rings vary from 2.014 (4) to 2.070 (3) Å, and are in the normal range. In the crystal, mol­ecules are linked by C—H⋯N inter­actions, forming an infinite two-dimensional network.
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spelling pubmed-29702542010-12-30 (R,R)-(N,N′-Diferrocenylcyclo­hexane-1,2-diyldiimino)dibenzonitrile Chen, Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(2)(C(5)H(5))(2)(C(34)H(34)N(4))], two ferrocenes are bridged by a cyclo­hexane-1,2-diamine unit. The cyclo­penta­dienyl rings of the two ferrocene units are almost parallel [dihedral angles of 0.7 (4) and 1.0 (4)° in the two units] and eclipsed, as is typically found for similar monosubstituted ferrocene derivatives. The dihedral angle formed by the two benzene rings is 20.2 (3)°. The Fe—C bond lengths to the two substituted Cp rings vary from 2.014 (4) to 2.070 (3) Å, and are in the normal range. In the crystal, mol­ecules are linked by C—H⋯N inter­actions, forming an infinite two-dimensional network. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970254/ /pubmed/21577729 http://dx.doi.org/10.1107/S1600536809035788 Text en © Fang Chen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Fang
(R,R)-(N,N′-Diferrocenylcyclo­hexane-1,2-diyldiimino)dibenzonitrile
title (R,R)-(N,N′-Diferrocenylcyclo­hexane-1,2-diyldiimino)dibenzonitrile
title_full (R,R)-(N,N′-Diferrocenylcyclo­hexane-1,2-diyldiimino)dibenzonitrile
title_fullStr (R,R)-(N,N′-Diferrocenylcyclo­hexane-1,2-diyldiimino)dibenzonitrile
title_full_unstemmed (R,R)-(N,N′-Diferrocenylcyclo­hexane-1,2-diyldiimino)dibenzonitrile
title_short (R,R)-(N,N′-Diferrocenylcyclo­hexane-1,2-diyldiimino)dibenzonitrile
title_sort (r,r)-(n,n′-diferrocenylcyclo­hexane-1,2-diyldiimino)dibenzonitrile
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970254/
https://www.ncbi.nlm.nih.gov/pubmed/21577729
http://dx.doi.org/10.1107/S1600536809035788
work_keys_str_mv AT chenfang rrnndiferrocenylcyclohexane12diyldiiminodibenzonitrile

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