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3-(6-Benzyloxy-2,2-dimethylperhydrofuro[2,3-d][1,3]dioxolan-5-yl)-5-(4-chlorophenyl)-4-nitro-2-phenyl-2,3,4,5-tetrahydroisoxazole
In the title compound, C(29)H(29)ClN(2)O(7), the isoxazole and dioxolane rings adopt envelope conformations, and the furan ring adopts a twisted conformation. The crystal structure is stabilized by intermolecular C—H⋯π interactions between a benzyloxy methylene H atom and the 4-chlorophenyl rin...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970260/ https://www.ncbi.nlm.nih.gov/pubmed/21577778 http://dx.doi.org/10.1107/S1600536809034096 |
Sumario: | In the title compound, C(29)H(29)ClN(2)O(7), the isoxazole and dioxolane rings adopt envelope conformations, and the furan ring adopts a twisted conformation. The crystal structure is stabilized by intermolecular C—H⋯π interactions between a benzyloxy methylene H atom and the 4-chlorophenyl ring of an adjacent molecule, and by weak non-classical intermolecular C—H⋯O hydrogen bonds. In addition, the crystal structure exhibits a Cl⋯O halogen bond of 3.111 (3) Å, with a nearly linear C—Cl⋯O angle of 160.7 (1)°. |
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