3-(6-Benz­yloxy-2,2-dimethyl­perhydro­furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro­phen­yl)-4-nitro-2-phenyl-2,3,4,5-tetra­hydro­isoxazole

In the title compound, C(29)H(29)ClN(2)O(7), the isoxazole and dioxolane rings adopt envelope conformations, and the furan ring adopts a twisted conformation. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions between a benz­yloxy methyl­ene H atom and the 4-chloro­phenyl rin...

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Detalles Bibliográficos
Autores principales: NizamMohideen, M., Damodiran, M., SubbiahPandi, A., Perumal, P. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970260/
https://www.ncbi.nlm.nih.gov/pubmed/21577778
http://dx.doi.org/10.1107/S1600536809034096
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author NizamMohideen, M.
Damodiran, M.
SubbiahPandi, A.
Perumal, P. T.
author_facet NizamMohideen, M.
Damodiran, M.
SubbiahPandi, A.
Perumal, P. T.
author_sort NizamMohideen, M.
collection PubMed
description In the title compound, C(29)H(29)ClN(2)O(7), the isoxazole and dioxolane rings adopt envelope conformations, and the furan ring adopts a twisted conformation. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions between a benz­yloxy methyl­ene H atom and the 4-chloro­phenyl ring of an adjacent mol­ecule, and by weak non-classical inter­molecular C—H⋯O hydrogen bonds. In addition, the crystal structure exhibits a Cl⋯O halogen bond of 3.111 (3) Å, with a nearly linear C—Cl⋯O angle of 160.7 (1)°.
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spelling pubmed-29702602010-12-30 3-(6-Benz­yloxy-2,2-dimethyl­perhydro­furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro­phen­yl)-4-nitro-2-phenyl-2,3,4,5-tetra­hydro­isoxazole NizamMohideen, M. Damodiran, M. SubbiahPandi, A. Perumal, P. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(29)H(29)ClN(2)O(7), the isoxazole and dioxolane rings adopt envelope conformations, and the furan ring adopts a twisted conformation. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions between a benz­yloxy methyl­ene H atom and the 4-chloro­phenyl ring of an adjacent mol­ecule, and by weak non-classical inter­molecular C—H⋯O hydrogen bonds. In addition, the crystal structure exhibits a Cl⋯O halogen bond of 3.111 (3) Å, with a nearly linear C—Cl⋯O angle of 160.7 (1)°. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970260/ /pubmed/21577778 http://dx.doi.org/10.1107/S1600536809034096 Text en © NizamMohideen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
NizamMohideen, M.
Damodiran, M.
SubbiahPandi, A.
Perumal, P. T.
3-(6-Benz­yloxy-2,2-dimethyl­perhydro­furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro­phen­yl)-4-nitro-2-phenyl-2,3,4,5-tetra­hydro­isoxazole
title 3-(6-Benz­yloxy-2,2-dimethyl­perhydro­furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro­phen­yl)-4-nitro-2-phenyl-2,3,4,5-tetra­hydro­isoxazole
title_full 3-(6-Benz­yloxy-2,2-dimethyl­perhydro­furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro­phen­yl)-4-nitro-2-phenyl-2,3,4,5-tetra­hydro­isoxazole
title_fullStr 3-(6-Benz­yloxy-2,2-dimethyl­perhydro­furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro­phen­yl)-4-nitro-2-phenyl-2,3,4,5-tetra­hydro­isoxazole
title_full_unstemmed 3-(6-Benz­yloxy-2,2-dimethyl­perhydro­furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro­phen­yl)-4-nitro-2-phenyl-2,3,4,5-tetra­hydro­isoxazole
title_short 3-(6-Benz­yloxy-2,2-dimethyl­perhydro­furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro­phen­yl)-4-nitro-2-phenyl-2,3,4,5-tetra­hydro­isoxazole
title_sort 3-(6-benz­yloxy-2,2-dimethyl­perhydro­furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro­phen­yl)-4-nitro-2-phenyl-2,3,4,5-tetra­hydro­isoxazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970260/
https://www.ncbi.nlm.nih.gov/pubmed/21577778
http://dx.doi.org/10.1107/S1600536809034096
work_keys_str_mv AT nizammohideenm 36benzyloxy22dimethylperhydrofuro23d13dioxolan5yl54chlorophenyl4nitro2phenyl2345tetrahydroisoxazole
AT damodiranm 36benzyloxy22dimethylperhydrofuro23d13dioxolan5yl54chlorophenyl4nitro2phenyl2345tetrahydroisoxazole
AT subbiahpandia 36benzyloxy22dimethylperhydrofuro23d13dioxolan5yl54chlorophenyl4nitro2phenyl2345tetrahydroisoxazole
AT perumalpt 36benzyloxy22dimethylperhydrofuro23d13dioxolan5yl54chlorophenyl4nitro2phenyl2345tetrahydroisoxazole

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