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4-(2-Methylpiperidin-1-ylcarbonyl)pyridinium hexachloridoantimonate(V)
In the hexachloridoanimonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octahedral coordination. In the 4-(2-methylpiperidine-1-carbonyl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 6...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970264/ https://www.ncbi.nlm.nih.gov/pubmed/21577742 http://dx.doi.org/10.1107/S1600536809036587 |
Sumario: | In the hexachloridoanimonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octahedral coordination. In the 4-(2-methylpiperidine-1-carbonyl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 66.3 (3)°. The mean plane of the carbonyl group is twisted by 80.5 (7)° and 42.7 (4)° relative to the mean planes of the pyridine and piperzine rings, respectively. The methyl group is in an R configuration relative to the piperidine ring which is in a slightly distorted chair conformation. The crystal packing is stabilized by N—H⋯O hydrogen bonds between cations, which form infinite zigzag chains parallel to [010]. |
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