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4-(2-Methyl­piperidin-1-ylcarbon­yl)pyridinium hexachloridoantimonate(V)

In the hexa­chlorido­animonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octa­hedral coordination. In the 4-(2-methyl­piperidine-1-carbon­yl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 6...

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Detalles Bibliográficos
Autor principal: Wang, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970264/
https://www.ncbi.nlm.nih.gov/pubmed/21577742
http://dx.doi.org/10.1107/S1600536809036587
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author Wang, Bo
author_facet Wang, Bo
author_sort Wang, Bo
collection PubMed
description In the hexa­chlorido­animonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octa­hedral coordination. In the 4-(2-methyl­piperidine-1-carbon­yl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 66.3 (3)°. The mean plane of the carbonyl group is twisted by 80.5 (7)° and 42.7 (4)° relative to the mean planes of the pyridine and piperzine rings, respectively. The methyl group is in an R configuration relative to the piperidine ring which is in a slightly distorted chair conformation. The crystal packing is stabilized by N—H⋯O hydrogen bonds between cations, which form infinite zigzag chains parallel to [010].
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spelling pubmed-29702642010-12-30 4-(2-Methyl­piperidin-1-ylcarbon­yl)pyridinium hexachloridoantimonate(V) Wang, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the hexa­chlorido­animonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octa­hedral coordination. In the 4-(2-methyl­piperidine-1-carbon­yl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 66.3 (3)°. The mean plane of the carbonyl group is twisted by 80.5 (7)° and 42.7 (4)° relative to the mean planes of the pyridine and piperzine rings, respectively. The methyl group is in an R configuration relative to the piperidine ring which is in a slightly distorted chair conformation. The crystal packing is stabilized by N—H⋯O hydrogen bonds between cations, which form infinite zigzag chains parallel to [010]. International Union of Crystallography 2009-09-16 /pmc/articles/PMC2970264/ /pubmed/21577742 http://dx.doi.org/10.1107/S1600536809036587 Text en © Bo Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Bo
4-(2-Methyl­piperidin-1-ylcarbon­yl)pyridinium hexachloridoantimonate(V)
title 4-(2-Methyl­piperidin-1-ylcarbon­yl)pyridinium hexachloridoantimonate(V)
title_full 4-(2-Methyl­piperidin-1-ylcarbon­yl)pyridinium hexachloridoantimonate(V)
title_fullStr 4-(2-Methyl­piperidin-1-ylcarbon­yl)pyridinium hexachloridoantimonate(V)
title_full_unstemmed 4-(2-Methyl­piperidin-1-ylcarbon­yl)pyridinium hexachloridoantimonate(V)
title_short 4-(2-Methyl­piperidin-1-ylcarbon­yl)pyridinium hexachloridoantimonate(V)
title_sort 4-(2-methyl­piperidin-1-ylcarbon­yl)pyridinium hexachloridoantimonate(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970264/
https://www.ncbi.nlm.nih.gov/pubmed/21577742
http://dx.doi.org/10.1107/S1600536809036587
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