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4-(2-Methylpiperidin-1-ylcarbonyl)pyridinium hexachloridoantimonate(V)
In the hexachloridoanimonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octahedral coordination. In the 4-(2-methylpiperidine-1-carbonyl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 6...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970264/ https://www.ncbi.nlm.nih.gov/pubmed/21577742 http://dx.doi.org/10.1107/S1600536809036587 |
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author | Wang, Bo |
author_facet | Wang, Bo |
author_sort | Wang, Bo |
collection | PubMed |
description | In the hexachloridoanimonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octahedral coordination. In the 4-(2-methylpiperidine-1-carbonyl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 66.3 (3)°. The mean plane of the carbonyl group is twisted by 80.5 (7)° and 42.7 (4)° relative to the mean planes of the pyridine and piperzine rings, respectively. The methyl group is in an R configuration relative to the piperidine ring which is in a slightly distorted chair conformation. The crystal packing is stabilized by N—H⋯O hydrogen bonds between cations, which form infinite zigzag chains parallel to [010]. |
format | Text |
id | pubmed-2970264 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29702642010-12-30 4-(2-Methylpiperidin-1-ylcarbonyl)pyridinium hexachloridoantimonate(V) Wang, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the hexachloridoanimonate anion of the title compound, (C(12)H(17)N(2)O)[SbCl(6)], the Sb(5+)ion is in a slightly distorted octahedral coordination. In the 4-(2-methylpiperidine-1-carbonyl) pyridinium cation, the dihedral angle between the mean planes of the pyridine and piperzine rings is 66.3 (3)°. The mean plane of the carbonyl group is twisted by 80.5 (7)° and 42.7 (4)° relative to the mean planes of the pyridine and piperzine rings, respectively. The methyl group is in an R configuration relative to the piperidine ring which is in a slightly distorted chair conformation. The crystal packing is stabilized by N—H⋯O hydrogen bonds between cations, which form infinite zigzag chains parallel to [010]. International Union of Crystallography 2009-09-16 /pmc/articles/PMC2970264/ /pubmed/21577742 http://dx.doi.org/10.1107/S1600536809036587 Text en © Bo Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Bo 4-(2-Methylpiperidin-1-ylcarbonyl)pyridinium hexachloridoantimonate(V) |
title | 4-(2-Methylpiperidin-1-ylcarbonyl)pyridinium hexachloridoantimonate(V) |
title_full | 4-(2-Methylpiperidin-1-ylcarbonyl)pyridinium hexachloridoantimonate(V) |
title_fullStr | 4-(2-Methylpiperidin-1-ylcarbonyl)pyridinium hexachloridoantimonate(V) |
title_full_unstemmed | 4-(2-Methylpiperidin-1-ylcarbonyl)pyridinium hexachloridoantimonate(V) |
title_short | 4-(2-Methylpiperidin-1-ylcarbonyl)pyridinium hexachloridoantimonate(V) |
title_sort | 4-(2-methylpiperidin-1-ylcarbonyl)pyridinium hexachloridoantimonate(v) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970264/ https://www.ncbi.nlm.nih.gov/pubmed/21577742 http://dx.doi.org/10.1107/S1600536809036587 |
work_keys_str_mv | AT wangbo 42methylpiperidin1ylcarbonylpyridiniumhexachloridoantimonatev |