Bis[5-(2-amino-3-pyrid­yl)tetra­zolato]copper(II)

In the centrosymmetric title complex, [Cu(C(6)H(5)N(6))(2)], the Cu(II) ion is coordinated by four N atoms from two symmetry-related bidentate 5-(2-amino-3-pyrid­yl)tetra­zolate ligands in a slightly distorted square-planar environment. There are weak intra­molecular N—H⋯N hydrogen bonds between the...

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Detalles Bibliográficos
Autor principal: Guo, Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970265/
https://www.ncbi.nlm.nih.gov/pubmed/21577699
http://dx.doi.org/10.1107/S1600536809034369
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author Guo, Min
author_facet Guo, Min
author_sort Guo, Min
collection PubMed
description In the centrosymmetric title complex, [Cu(C(6)H(5)N(6))(2)], the Cu(II) ion is coordinated by four N atoms from two symmetry-related bidentate 5-(2-amino-3-pyrid­yl)tetra­zolate ligands in a slightly distorted square-planar environment. There are weak intra­molecular N—H⋯N hydrogen bonds between the two ligands. In the crystal structure, there are significant π–π stacking inter­actions between symmetry-related tetra­zole and pyridine rings, with a centroid–centroid distance of 3.6025 (18)°.
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spelling pubmed-29702652010-12-30 Bis[5-(2-amino-3-pyrid­yl)tetra­zolato]copper(II) Guo, Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title complex, [Cu(C(6)H(5)N(6))(2)], the Cu(II) ion is coordinated by four N atoms from two symmetry-related bidentate 5-(2-amino-3-pyrid­yl)tetra­zolate ligands in a slightly distorted square-planar environment. There are weak intra­molecular N—H⋯N hydrogen bonds between the two ligands. In the crystal structure, there are significant π–π stacking inter­actions between symmetry-related tetra­zole and pyridine rings, with a centroid–centroid distance of 3.6025 (18)°. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970265/ /pubmed/21577699 http://dx.doi.org/10.1107/S1600536809034369 Text en © Min Guo 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Min
Bis[5-(2-amino-3-pyrid­yl)tetra­zolato]copper(II)
title Bis[5-(2-amino-3-pyrid­yl)tetra­zolato]copper(II)
title_full Bis[5-(2-amino-3-pyrid­yl)tetra­zolato]copper(II)
title_fullStr Bis[5-(2-amino-3-pyrid­yl)tetra­zolato]copper(II)
title_full_unstemmed Bis[5-(2-amino-3-pyrid­yl)tetra­zolato]copper(II)
title_short Bis[5-(2-amino-3-pyrid­yl)tetra­zolato]copper(II)
title_sort bis[5-(2-amino-3-pyrid­yl)tetra­zolato]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970265/
https://www.ncbi.nlm.nih.gov/pubmed/21577699
http://dx.doi.org/10.1107/S1600536809034369
work_keys_str_mv AT guomin bis52amino3pyridyltetrazolatocopperii

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