Cargando…

catena-Poly[bis­(4-amino­pyridinium) [[tetra­aqua­nickel(II)]-μ-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]

The asymmetric unit of the title compound, {(C(5)H(7)N(2))(2)[Ni(C(10)H(2)O(8))(H(2)O)(4)]·2H(2)O}(n), contains an Ni(II) atom, two water mol­ecules of coordination, one half of a benzene-1,2,4,5-tetra­carboxyl­ate (btec) anionic ligand, one 4-amino­pyridinium cation (papy) and an uncoordinated wate...

Descripción completa

Detalles Bibliográficos
Autores principales: Rotondo, Archimede, Bruno, Giuseppe, Messina, Fabio, Nicoló, Francesco
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970276/
https://www.ncbi.nlm.nih.gov/pubmed/21577731
http://dx.doi.org/10.1107/S1600536809034746
_version_ 1782190399161368576
author Rotondo, Archimede
Bruno, Giuseppe
Messina, Fabio
Nicoló, Francesco
author_facet Rotondo, Archimede
Bruno, Giuseppe
Messina, Fabio
Nicoló, Francesco
author_sort Rotondo, Archimede
collection PubMed
description The asymmetric unit of the title compound, {(C(5)H(7)N(2))(2)[Ni(C(10)H(2)O(8))(H(2)O)(4)]·2H(2)O}(n), contains an Ni(II) atom, two water mol­ecules of coordination, one half of a benzene-1,2,4,5-tetra­carboxyl­ate (btec) anionic ligand, one 4-amino­pyridinium cation (papy) and an uncoordinated water mol­ecule. The metal center lies on an inversion center and adopts an octa­hedral geometry with the carboxyl­ate groups tilted out of the mean plane formed by the btec. In the crystal, mol­ecules are linked into one-dimensional coordination polymers running along the ac diagonal. The crystal structure is consolidated by N—H⋯O and O—H⋯O hydrogen bonds.
format Text
id pubmed-2970276
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29702762010-12-30 catena-Poly[bis­(4-amino­pyridinium) [[tetra­aqua­nickel(II)]-μ-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate] Rotondo, Archimede Bruno, Giuseppe Messina, Fabio Nicoló, Francesco Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {(C(5)H(7)N(2))(2)[Ni(C(10)H(2)O(8))(H(2)O)(4)]·2H(2)O}(n), contains an Ni(II) atom, two water mol­ecules of coordination, one half of a benzene-1,2,4,5-tetra­carboxyl­ate (btec) anionic ligand, one 4-amino­pyridinium cation (papy) and an uncoordinated water mol­ecule. The metal center lies on an inversion center and adopts an octa­hedral geometry with the carboxyl­ate groups tilted out of the mean plane formed by the btec. In the crystal, mol­ecules are linked into one-dimensional coordination polymers running along the ac diagonal. The crystal structure is consolidated by N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970276/ /pubmed/21577731 http://dx.doi.org/10.1107/S1600536809034746 Text en © Rotondo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rotondo, Archimede
Bruno, Giuseppe
Messina, Fabio
Nicoló, Francesco
catena-Poly[bis­(4-amino­pyridinium) [[tetra­aqua­nickel(II)]-μ-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title catena-Poly[bis­(4-amino­pyridinium) [[tetra­aqua­nickel(II)]-μ-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title_full catena-Poly[bis­(4-amino­pyridinium) [[tetra­aqua­nickel(II)]-μ-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title_fullStr catena-Poly[bis­(4-amino­pyridinium) [[tetra­aqua­nickel(II)]-μ-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title_full_unstemmed catena-Poly[bis­(4-amino­pyridinium) [[tetra­aqua­nickel(II)]-μ-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title_short catena-Poly[bis­(4-amino­pyridinium) [[tetra­aqua­nickel(II)]-μ-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title_sort catena-poly[bis­(4-amino­pyridinium) [[tetra­aqua­nickel(ii)]-μ-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970276/
https://www.ncbi.nlm.nih.gov/pubmed/21577731
http://dx.doi.org/10.1107/S1600536809034746
work_keys_str_mv AT rotondoarchimede catenapolybis4aminopyridiniumtetraaquanickeliimbenzene1245tetracarboxylatodihydrate
AT brunogiuseppe catenapolybis4aminopyridiniumtetraaquanickeliimbenzene1245tetracarboxylatodihydrate
AT messinafabio catenapolybis4aminopyridiniumtetraaquanickeliimbenzene1245tetracarboxylatodihydrate
AT nicolofrancesco catenapolybis4aminopyridiniumtetraaquanickeliimbenzene1245tetracarboxylatodihydrate