catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-di­yl)diimidazole-κ(2) N (3):N (3′)]

In the structure of the polymeric title compound, [ZnCl(2)(C(12)H(18)N(4))](n) or [ZnCl(2)(L)](n), where L = 1,1′-(hexane-1,6-di­yl)diimidazole, the Zn(II) centre is coordinated by two N atoms of two different L ligands and by two chloride anions in a distorted tetra­hedral geometry. The organic lig...

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Detalles Bibliográficos
Autor principal: Bao, Wen-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970280/
https://www.ncbi.nlm.nih.gov/pubmed/21577757
http://dx.doi.org/10.1107/S1600536809037696
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author Bao, Wen-Li
author_facet Bao, Wen-Li
author_sort Bao, Wen-Li
collection PubMed
description In the structure of the polymeric title compound, [ZnCl(2)(C(12)H(18)N(4))](n) or [ZnCl(2)(L)](n), where L = 1,1′-(hexane-1,6-di­yl)diimidazole, the Zn(II) centre is coordinated by two N atoms of two different L ligands and by two chloride anions in a distorted tetra­hedral geometry. The organic ligand links adjacent metals to form a polymeric chain along the c axis. The chains are further connected into layers parallel to the bc plane by inter­molecular C—H⋯Cl hydrogen bonds. Two C atoms of the central hexyl chain are disordered over two positions with site-occupancy factors of 0.5.
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spelling pubmed-29702802010-12-30 catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-di­yl)diimidazole-κ(2) N (3):N (3′)] Bao, Wen-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the polymeric title compound, [ZnCl(2)(C(12)H(18)N(4))](n) or [ZnCl(2)(L)](n), where L = 1,1′-(hexane-1,6-di­yl)diimidazole, the Zn(II) centre is coordinated by two N atoms of two different L ligands and by two chloride anions in a distorted tetra­hedral geometry. The organic ligand links adjacent metals to form a polymeric chain along the c axis. The chains are further connected into layers parallel to the bc plane by inter­molecular C—H⋯Cl hydrogen bonds. Two C atoms of the central hexyl chain are disordered over two positions with site-occupancy factors of 0.5. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970280/ /pubmed/21577757 http://dx.doi.org/10.1107/S1600536809037696 Text en © Wen-Li Bao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bao, Wen-Li
catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-di­yl)diimidazole-κ(2) N (3):N (3′)]
title catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-di­yl)diimidazole-κ(2) N (3):N (3′)]
title_full catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-di­yl)diimidazole-κ(2) N (3):N (3′)]
title_fullStr catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-di­yl)diimidazole-κ(2) N (3):N (3′)]
title_full_unstemmed catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-di­yl)diimidazole-κ(2) N (3):N (3′)]
title_short catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-di­yl)diimidazole-κ(2) N (3):N (3′)]
title_sort catena-poly[[dichloridozinc(ii)]-μ-1,1′-(hexane-1,6-di­yl)diimidazole-κ(2) n (3):n (3′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970280/
https://www.ncbi.nlm.nih.gov/pubmed/21577757
http://dx.doi.org/10.1107/S1600536809037696
work_keys_str_mv AT baowenli catenapolydichloridozinciim11hexane16diyldiimidazolek2n3n3

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