Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(II)

In the title compound, [Ni(C(8)H(7)O(4))(2){(CH(3))(2)SO}(2)], the Ni(II) atom is located on a crystallographic centre of symmetry and has a distorted octa­hedral coordination geometry of type MO(6). The bidentate dehydro­acetic acid (DHA) ligands occupy the equatorial plane of the complex in a tran...

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Detalles Bibliográficos
Autores principales: Djedouani, Amel, Boufas, Sihem, Bendaas, Abderrahmen, Allain, Magali, Bouet, Gilles
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970285/
https://www.ncbi.nlm.nih.gov/pubmed/21577732
http://dx.doi.org/10.1107/S1600536809034655
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author Djedouani, Amel
Boufas, Sihem
Bendaas, Abderrahmen
Allain, Magali
Bouet, Gilles
author_facet Djedouani, Amel
Boufas, Sihem
Bendaas, Abderrahmen
Allain, Magali
Bouet, Gilles
author_sort Djedouani, Amel
collection PubMed
description In the title compound, [Ni(C(8)H(7)O(4))(2){(CH(3))(2)SO}(2)], the Ni(II) atom is located on a crystallographic centre of symmetry and has a distorted octa­hedral coordination geometry of type MO(6). The bidentate dehydro­acetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and the dimethyl sulfoxide (DMSO) ligands are weakly coordinated through their O atoms in the axial positions.
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spelling pubmed-29702852010-12-30 Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(II) Djedouani, Amel Boufas, Sihem Bendaas, Abderrahmen Allain, Magali Bouet, Gilles Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(7)O(4))(2){(CH(3))(2)SO}(2)], the Ni(II) atom is located on a crystallographic centre of symmetry and has a distorted octa­hedral coordination geometry of type MO(6). The bidentate dehydro­acetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and the dimethyl sulfoxide (DMSO) ligands are weakly coordinated through their O atoms in the axial positions. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970285/ /pubmed/21577732 http://dx.doi.org/10.1107/S1600536809034655 Text en © Djedouani et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Djedouani, Amel
Boufas, Sihem
Bendaas, Abderrahmen
Allain, Magali
Bouet, Gilles
Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(II)
title Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(II)
title_full Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(II)
title_fullStr Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(II)
title_full_unstemmed Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(II)
title_short Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(II)
title_sort bis(3-acetyl-6-methyl-2-oxo-2h-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970285/
https://www.ncbi.nlm.nih.gov/pubmed/21577732
http://dx.doi.org/10.1107/S1600536809034655
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