catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth­yl)methyl­ene]glycinato]

In the title compound, [Cu(C(13)H(9)NO(3))(C(5)H(5)N)], the Cu(II) atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu—O bond [2.3520 (16) Å] is much longer than the basal Cu—O and Cu—N b...

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Detalles Bibliográficos
Autores principales: Xue, Ling-Wei, Li, Xing-Wu, Zhao, Gan-Qing, Peng, Qin-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970287/
https://www.ncbi.nlm.nih.gov/pubmed/21577755
http://dx.doi.org/10.1107/S1600536809037520
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author Xue, Ling-Wei
Li, Xing-Wu
Zhao, Gan-Qing
Peng, Qin-Long
author_facet Xue, Ling-Wei
Li, Xing-Wu
Zhao, Gan-Qing
Peng, Qin-Long
author_sort Xue, Ling-Wei
collection PubMed
description In the title compound, [Cu(C(13)H(9)NO(3))(C(5)H(5)N)], the Cu(II) atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu—O bond [2.3520 (16) Å] is much longer than the basal Cu—O and Cu—N bonds [1.9139 (14)–2.0136 (17) Å]. The carboxyl­ate group bridges Cu(II) atoms, forming a zigzag chain along the a axis.
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spelling pubmed-29702872010-12-30 catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth­yl)methyl­ene]glycinato] Xue, Ling-Wei Li, Xing-Wu Zhao, Gan-Qing Peng, Qin-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(13)H(9)NO(3))(C(5)H(5)N)], the Cu(II) atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu—O bond [2.3520 (16) Å] is much longer than the basal Cu—O and Cu—N bonds [1.9139 (14)–2.0136 (17) Å]. The carboxyl­ate group bridges Cu(II) atoms, forming a zigzag chain along the a axis. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970287/ /pubmed/21577755 http://dx.doi.org/10.1107/S1600536809037520 Text en © Xue et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xue, Ling-Wei
Li, Xing-Wu
Zhao, Gan-Qing
Peng, Qin-Long
catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth­yl)methyl­ene]glycinato]
title catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth­yl)methyl­ene]glycinato]
title_full catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth­yl)methyl­ene]glycinato]
title_fullStr catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth­yl)methyl­ene]glycinato]
title_full_unstemmed catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth­yl)methyl­ene]glycinato]
title_short catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth­yl)methyl­ene]glycinato]
title_sort catena-poly[[pyridinecopper(ii)]-μ-n-[(2-oxido-1-naphth­yl)methyl­ene]glycinato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970287/
https://www.ncbi.nlm.nih.gov/pubmed/21577755
http://dx.doi.org/10.1107/S1600536809037520
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