11β,13-Dihydro­lactucin-8-O-acetate hemihydrate

The title structure (systematic name: 9-hydroxy­methyl-3,6-di­methyl-3-methyl­ene-2,7-dioxo-3,3a,4,5,9a,9b-hexa­hydro­azu­leno[4,5-b]furan-4-yl acetate hemihydrate), C(17)H(20)O(6)·0.5H(2)O, from Lactuca floridana, has two independent sesquiterpene lactone mol­ecules in the asymmetric unit. Both hav...

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Detalles Bibliográficos
Autores principales: Fronczek, Chris F., Gomez-Barrios, Marco L., Fischer, Nikolaus H., Fronczek, Frank R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970292/
https://www.ncbi.nlm.nih.gov/pubmed/21578003
http://dx.doi.org/10.1107/S160053680903829X
Descripción
Sumario:The title structure (systematic name: 9-hydroxy­methyl-3,6-di­methyl-3-methyl­ene-2,7-dioxo-3,3a,4,5,9a,9b-hexa­hydro­azu­leno[4,5-b]furan-4-yl acetate hemihydrate), C(17)H(20)O(6)·0.5H(2)O, from Lactuca floridana, has two independent sesquiterpene lactone mol­ecules in the asymmetric unit. Both have their seven-membered rings in the chair conformation. In the crystal, the OH groups and the water mol­ecule form classical O—H⋯O hydrogen bonds with O⋯O distances in the range 2.6750 (17)–2.8160 (18) Å.

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