2,4,6,8-Tetra­kis(2-methoxy­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one diethyl ether hemisolvate

In the title compound, C(35)H(36)N(2)O(5)·0.5C(4)H(10)O, the asymmetric unit contains one bicyclo­[3.3.1]nonane mol­ecule and a half-occupancy diethyl ether solvent with the O atom lying on a crystallographic inversion center. Two intra­molecular N—H⋯O hydrogen bonds generate S(6) ring motifs. The b...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Yeap, Chin Sing, Rajesh, K., Sarveswari, S., Vijayakumar, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970300/
https://www.ncbi.nlm.nih.gov/pubmed/21577937
http://dx.doi.org/10.1107/S1600536809036733
Descripción
Sumario:In the title compound, C(35)H(36)N(2)O(5)·0.5C(4)H(10)O, the asymmetric unit contains one bicyclo­[3.3.1]nonane mol­ecule and a half-occupancy diethyl ether solvent with the O atom lying on a crystallographic inversion center. Two intra­molecular N—H⋯O hydrogen bonds generate S(6) ring motifs. The bicyclo­[3.3.1]nonane ring system adopts a chair-boat conformation. In the crystal structure, the mol­ecules are linked by weak inter­molecular C—H⋯N hydro­gen bonds into chains along the b axis; additional stabilization is provide by C—H⋯π inter­actions.

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