2,4,6,8-Tetra­kis(2-methoxy­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one diethyl ether hemisolvate

In the title compound, C(35)H(36)N(2)O(5)·0.5C(4)H(10)O, the asymmetric unit contains one bicyclo­[3.3.1]nonane mol­ecule and a half-occupancy diethyl ether solvent with the O atom lying on a crystallographic inversion center. Two intra­molecular N—H⋯O hydrogen bonds generate S(6) ring motifs. The b...

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Autores principales: Fun, Hoong-Kun, Yeap, Chin Sing, Rajesh, K., Sarveswari, S., Vijayakumar, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970300/
https://www.ncbi.nlm.nih.gov/pubmed/21577937
http://dx.doi.org/10.1107/S1600536809036733
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author Fun, Hoong-Kun
Yeap, Chin Sing
Rajesh, K.
Sarveswari, S.
Vijayakumar, V.
author_facet Fun, Hoong-Kun
Yeap, Chin Sing
Rajesh, K.
Sarveswari, S.
Vijayakumar, V.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(35)H(36)N(2)O(5)·0.5C(4)H(10)O, the asymmetric unit contains one bicyclo­[3.3.1]nonane mol­ecule and a half-occupancy diethyl ether solvent with the O atom lying on a crystallographic inversion center. Two intra­molecular N—H⋯O hydrogen bonds generate S(6) ring motifs. The bicyclo­[3.3.1]nonane ring system adopts a chair-boat conformation. In the crystal structure, the mol­ecules are linked by weak inter­molecular C—H⋯N hydro­gen bonds into chains along the b axis; additional stabilization is provide by C—H⋯π inter­actions.
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spelling pubmed-29703002010-12-30 2,4,6,8-Tetra­kis(2-methoxy­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one diethyl ether hemisolvate Fun, Hoong-Kun Yeap, Chin Sing Rajesh, K. Sarveswari, S. Vijayakumar, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(35)H(36)N(2)O(5)·0.5C(4)H(10)O, the asymmetric unit contains one bicyclo­[3.3.1]nonane mol­ecule and a half-occupancy diethyl ether solvent with the O atom lying on a crystallographic inversion center. Two intra­molecular N—H⋯O hydrogen bonds generate S(6) ring motifs. The bicyclo­[3.3.1]nonane ring system adopts a chair-boat conformation. In the crystal structure, the mol­ecules are linked by weak inter­molecular C—H⋯N hydro­gen bonds into chains along the b axis; additional stabilization is provide by C—H⋯π inter­actions. International Union of Crystallography 2009-09-19 /pmc/articles/PMC2970300/ /pubmed/21577937 http://dx.doi.org/10.1107/S1600536809036733 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Yeap, Chin Sing
Rajesh, K.
Sarveswari, S.
Vijayakumar, V.
2,4,6,8-Tetra­kis(2-methoxy­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one diethyl ether hemisolvate
title 2,4,6,8-Tetra­kis(2-methoxy­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one diethyl ether hemisolvate
title_full 2,4,6,8-Tetra­kis(2-methoxy­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one diethyl ether hemisolvate
title_fullStr 2,4,6,8-Tetra­kis(2-methoxy­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one diethyl ether hemisolvate
title_full_unstemmed 2,4,6,8-Tetra­kis(2-methoxy­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one diethyl ether hemisolvate
title_short 2,4,6,8-Tetra­kis(2-methoxy­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one diethyl ether hemisolvate
title_sort 2,4,6,8-tetra­kis(2-methoxy­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one diethyl ether hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970300/
https://www.ncbi.nlm.nih.gov/pubmed/21577937
http://dx.doi.org/10.1107/S1600536809036733
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